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The catalytic activities of the Au−Ag:PVP clusters were investigated for aerobic oxidation of p-hydroxybenzyl alcohol as a model reaction to understand the effect of Ag on the catalytic activity of Au clusters. It was found that the rate constants per unit surface area for Au−Ag:PVP clusters with small Ag content (<10%) were larger than those of monometallic Au:PVP clusters of comparable size. The enhancement of the catalytic activity by Ag doping is discussed in light of the electronic structure of the Au−Ag cores probed by X-ray photoelectron spectroscopy. The present results indicate that the partial anionic character of the Au core is important for the aerobic oxidation reactions of Au:PVP clusters."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137045537848961","@type":"Researcher","foaf:name":[{"@value":"Nirmalya K. 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