{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361137045649301376.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1007/s00216-003-2476-y"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s00216-003-2476-y.pdf"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/article/10.1007/s00216-003-2476-y/fulltext.html"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s00216-003-2476-y"}},{"identifier":{"@type":"PMID","@value":"14747893"}}],"dc:title":[{"@value":"Simultaneous determination of bismuth and tellurium in steels by high power nitrogen microwave induced plasma atomic emission spectrometry coupled with the hydride generation technique"}],"description":[{"notation":[{"@value":"An annular-shaped, high power nitrogen microwave induced plasma (N(2)-MIP) produced at atmospheric pressure by an Okamoto cavity, as a new excitation source for atomic emission spectrometry (AES), has been used for the simultaneous determination of bismuth and tellurium in steels with the hydride generation method. Under the optimized experimental conditions, the best attainable detection limits at the Bi I 195.389 nm and Te I 200.200 nm lines were 110 and 86 ng/ml for bismuth and tellurium, respectively. The linear dynamic ranges for bismuth and tellurium were 300 to 30,000 ng/ml. The presence of several diverse elements was found to cause a more or less depressing interference with the proposed technique. When bismuth and tellurium in steels were determined, a large amount of Fe(III) in the solution caused a severe depressing interference, while the presence of Fe(II) showed little or no significant interference. Of the several interference-releasing agents examined, l-ascorbic acid was found to be the most preferable to reduce Fe(III) to Fe(II) prior to hydride generation. The concentrations of bismuth and tellurium in steels were determined by the proposed technique. The results obtained by this method were in good agreement with their certified values."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137045649301378","@type":"Researcher","foaf:name":[{"@value":"Akihiro Matsumoto"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137045649301377","@type":"Researcher","foaf:name":[{"@value":"Tadashi Shiozaki"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137045649301376","@type":"Researcher","foaf:name":[{"@value":"Taketoshi Nakahara"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16182642"},{"@type":"EISSN","@value":"16182650"},{"@type":"PISSN","@value":"http://id.crossref.org/issn/16182642"}],"prism:publicationName":[{"@value":"Analytical and Bioanalytical Chemistry"}],"dc:publisher":[{"@value":"Springer Science and Business Media LLC"}],"prism:publicationDate":"2004-05-01","prism:volume":"379","prism:number":"1","prism:startingPage":"90","prism:endingPage":"95"},"reviewed":"false","dc:rights":["http://www.springer.com/tdm"],"url":[{"@id":"http://link.springer.com/content/pdf/10.1007/s00216-003-2476-y.pdf"},{"@id":"http://link.springer.com/article/10.1007/s00216-003-2476-y/fulltext.html"},{"@id":"http://link.springer.com/content/pdf/10.1007/s00216-003-2476-y"}],"createdAt":"2004-01-28","modifiedAt":"2019-05-23","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Biochemistry","dc:title":"Biochemistry"},{"@id":"https://cir.nii.ac.jp/all?q=Analytical%20Chemistry","dc:title":"Analytical Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390282679232477568","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Gas-Phase Sample-Introduction Techniques for Analytical Atomic Spectrometry"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679331712384","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Determination of lead in steel by high power nitrogen microwave induced plasma atomic emission spectrometry coupled with hydride generation technique"},{"@language":"ja","@value":"水素化物生成‐高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼中の鉛の定量"},{"@value":"水素化物生成-高出力窒素マイクロ波誘導プラズマ発光分光分析による鉄鋼中の鉛の定量"},{"@language":"ja-Kana","@value":"スイソカブツ セイセイ コウシュツリョク チッソ マイクロハ ユウドウ プラズマ ハッコウ ブンコウ ブンセキ ニ ヨル テッコウ チュウ ノ ナマリ ノ テイリョウ"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1007/s00216-003-2476-y"},{"@type":"OPENAIRE","@value":"doi_dedup___::0a4e0fcc6250816d9b1e3d962ec8d9ea"},{"@type":"CROSSREF","@value":"10.2116/bunsekikagaku.53.1157_references_DOI_FnfRgn44SMdnkG8WkLpDTJwJg9N"},{"@type":"CROSSREF","@value":"10.2116/analsci.21.477_references_DOI_FnfRgn44SMdnkG8WkLpDTJwJg9N"}]}