{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361412889399570688.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/asia.201901745"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fasia.201901745"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/asia.201901745"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/asia.201901745"}},{"identifier":{"@type":"URI","@value":"https://aces.onlinelibrary.wiley.com/doi/pdf/10.1002/asia.201901745"}},{"identifier":{"@type":"PMID","@value":"31903690"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Rhodium(I)/Chiral Diene‐Catalyzed Enantioselective Addition of Boronic Acids to <i>N</i>‐Unsubstituted Isatin‐Derived Ketimines"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Enantioselective addition of boronic acids to <jats:italic>N</jats:italic>‐unsubstituted isatin‐derived ketimines was realized using rhodium(I)/chiral diene catalysts. The reactions can be performed in the presence of catalytic amounts of a base to give adducts in high yield with high enantioselectivity. Preliminary mechanistic information including a computational model to explain the observed enantioselectivity is also provided.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381412889399570817","@type":"Researcher","foaf:name":[{"@value":"Ryohei Yonesaki"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences Kyushu University  Maidashi 3-1-1 Higashi-ku Fukuoka 812-8582 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412889399570818","@type":"Researcher","foaf:name":[{"@value":"Ibuki Kusagawa"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences Kyushu University  Maidashi 3-1-1 Higashi-ku Fukuoka 812-8582 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420282801184246400","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20593867"},{"@type":"NRID","@value":"1000020593867"},{"@type":"NRID","@value":"9000282424181"},{"@type":"NRID","@value":"9000408919848"},{"@type":"NRID","@value":"9000399524003"},{"@type":"NRID","@value":"9000409882848"},{"@type":"NRID","@value":"9000008309037"},{"@type":"NRID","@value":"9000256438373"},{"@type":"NRID","@value":"9000006391149"},{"@type":"NRID","@value":"9000006299105"},{"@type":"NRID","@value":"9000383743609"},{"@type":"NRID","@value":"9000414925886"},{"@type":"NRID","@value":"9000256433297"},{"@type":"NRID","@value":"9000369747231"},{"@type":"NRID","@value":"9000396141841"},{"@type":"NRID","@value":"9000256438955"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/Hiroyuki_Morimoto"}],"foaf:name":[{"@value":"Hiroyuki Morimoto"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences Kyushu University  Maidashi 3-1-1 Higashi-ku Fukuoka 812-8582 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412889399570689","@type":"Researcher","foaf:name":[{"@value":"Tamio Hayashi"}],"jpcoar:affiliationName":[{"@value":"Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University  21 Nanyang Link Singapore 637371 Singapore"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412889399570816","@type":"Researcher","foaf:name":[{"@value":"Takashi Ohshima"}],"jpcoar:affiliationName":[{"@value":"Graduate School of Pharmaceutical Sciences Kyushu University  Maidashi 3-1-1 Higashi-ku Fukuoka 812-8582 Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"18614728"},{"@type":"EISSN","@value":"1861471X"}],"prism:publicationName":[{"@value":"Chemistry – An Asian Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2020-01-24","prism:volume":"15","prism:number":"4","prism:startingPage":"499","prism:endingPage":"502"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fasia.201901745"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/asia.201901745"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/asia.201901745"},{"@id":"https://aces.onlinelibrary.wiley.com/doi/pdf/10.1002/asia.201901745"}],"createdAt":"2020-01-06","modifiedAt":"2025-10-08","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000781833993216","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"15H05846"},{"@type":"JGN","@value":"JP15H05846"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-15H05846/"}],"notation":[{"@language":"ja","@value":"環境調和反応の集積化"},{"@language":"en","@value":"Integration of Environmentally Friendly Direct Transformations"}]},{"@id":"https://cir.nii.ac.jp/crid/1040000781957306368","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"17H03972"},{"@type":"JGN","@value":"JP17H03972"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17H03972/"}],"notation":[{"@language":"ja","@value":"無保護ケチミンを用いる不斉四置換炭素含有第一級アミンの直接的触媒的合成法の開発"},{"@language":"en","@value":"Development of Direct Catalytic Synthesis of Primary Amine Containing Chiral Tetrasubstituted Carbon Using Unprotected Ketimine"}]},{"@id":"https://cir.nii.ac.jp/crid/1040000781960809344","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"17J02790"},{"@type":"JGN","@value":"JP17J02790"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17J02790/"}],"notation":[{"@language":"ja","@value":"α位に不斉四置換炭素を有するアミン類の新規触媒的合成法の開発"}]},{"@id":"https://cir.nii.ac.jp/crid/1040000781999718912","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"18K06581"},{"@type":"JGN","@value":"JP18K06581"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K06581/"}],"notation":[{"@language":"ja","@value":"無保護非天然アミノ酸類の直接合成を指向した新規環境調和型触媒反応の開発"},{"@language":"en","@value":"Development of New Environmentally Friendly Catalytic Reactions for the Direct Synthesis of Unprotected Unnatural Amino Acids"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002214426148736","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Synthesis of 2<i>H</i>‐Azirines with a Tetrasubstituted Stereocenter by Enantioselective Ring Contraction of Isoxazoles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233142703104","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Catalytic Enantioselective Decarboxylative Mannich-Type Reaction of<i>N</i>-Unprotected Isatin-Derived Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360005518008262528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Convenient Preparation Method for Benzophenone Imine Catalyzed by Tetrabutylammonium Fluoride"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011143942452608","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rhodium‐Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Allenes by the [3+2] Annulation of Aryl Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144081803520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<i>N</i>-(Heteroarenesulfonyl)prolinamides-Catalyzed Aldol Reaction between Acetone and Aryl Trihalomethyl Ketones"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145726215680","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Chiral Chelating Diene as a New Type of Chiral Ligand for Transition Metal Catalysts:  Its Preparation and Use for the Rhodium-Catalyzed Asymmetric 1,4-Addition"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011146088487680","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rhodium-Catalyzed Asymmetric Arylation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360016864412158080","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of <i>N</i>-Unprotected Diaryl Ketimines and Alkyl Ketimines from Ketones and Ammonia Using Porous Solid Acids with Analysis of Their Adsorption Behavior"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017279829764224","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Organocatalytic Direct Enantioselective Hydrophosphonylation of\n                    <i>N</i>\n                    -Unsubstituted Ketimines for the Synthesis of α-Aminophosphonates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021390745105920","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Development of Novel Catalytic Direct Syntheses of N-Unsubstituted Ketimines and Their Applications to One-Pot Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691635111424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Synthesis of (Triaryl)methylamines by Rhodium-Catalyzed Addition of Arylboroxines to Cyclic <i>N</i>-Sulfonyl Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285704898983424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α‐Oxo‐ and Iminocarboxamides with 1,3‐Dienes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708192397696","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chiral Metal Nanoparticle Systems as Heterogeneous Catalysts beyond Homogeneous Metal Complex Catalysts for Asymmetric Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360290617843532288","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Recent Progress on Catalytic Addition Reactions to<i>N</i>-Unsubstituted Imines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619004669568","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rh/Pd Catalysis with Chiral and Achiral Ligands: Domino Synthesis of Aza‐Dihydrodibenzoxepines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620117540352","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ligand-Controlled Rhodium-Catalyzed Site-Selective Asymmetric Addition of Arylboronic Acids to α,β-Unsaturated Cyclic <i>N</i>-Sulfonyl Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166635354112","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rhodium-Catalyzed Asymmetric Addition of Potassium Organotrifluoroborates to <i>N</i>-Sulfonyl Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567179950555776","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Friedel–Crafts Alkylation Reaction of Heteroarenes with N‐Unprotected Trifluoromethyl Ketimines by Means of Chiral Phosphoric Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360568467274973184","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent advances of achiral and chiral diene ligands in transition-metal catalyses"}]},{"@id":"https://cir.nii.ac.jp/crid/1360568467964131840","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Scandium(III) Triflate Catalyzed Direct Synthesis of <i>N</i>-Unprotected Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095986567296","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent Developments and Perspectives in the Asymmetric Mannich Reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846639397618944","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Direct Access to N‐Unprotected α‐ and/or β‐Tetrasubstituted Amino Acid Esters via Direct Catalytic Mannich‐Type Reactions Using N‐Unprotected Trifluoromethyl Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848654926722688","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"3‐Mono‐Substituted BINOL Phosphoric Acids as Effective Organocatalysts in Direct Enantioselective Friedel–Crafts‐Type Alkylation of N‐Unprotected α‐Ketiminoester"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658072115328","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Arylation of Imines Catalyzed by Heterogeneous Chiral Rhodium Nanoparticles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658543966848","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Direct access to N-unprotected tetrasubstituted propargylamines via direct catalytic alkynylation of N-unprotected trifluoromethyl ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569235881216","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Readily Available [2.2.2]-Bicyclooctadienes as New Chiral Ligands for Ir(I):  Catalytic, Kinetic Resolution of Allyl Carbonates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570204065152","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570433732352","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Rhodium‐Catalyzed Addition of Arylboroxines to N‐Unprotected Ketimines: Efficient Synthesis of Cipargamin"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865814738257408","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Development and Integration of New Green Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137043676511360","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"More than Bystanders: The Effect of Olefins on Transition‐Metal‐Catalyzed Cross‐Coupling Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137043862987648","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ni(<scp>ii</scp>)-catalyzed asymmetric addition of arylboronic acids to cyclic imines"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044315063808","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Convenient enantioselective synthesis of β-trifluoromethyl-β-aminoketones by organocatalytic asymmetric Mannich reaction of aryl trifluoromethyl ketimines with acetone"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044458446336","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045623217920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Nicht ganz unbeteiligt: der Einfluss von Olefinen auf übergangsmetallkatalysierte Kreuzkupplungen"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046025612288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric synthesis of phosphonotrifluoroalanine derivatives via proline-catalyzed direct enantioselective C C bond formation reactions of N H trifluoroacetimidoyl phosphonate"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046292085504","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rhenium and base co-catalyzed [3 + 2] annulations of N–H ketimines and alkynes to access unprotected tertiary indenamines through C–H bond activation"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046302221184","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Rhodium(I)‐Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed CH Activations"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418518952108672","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520402109952","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Catalytic Enantioselective Strecker Reaction of Isatin-Derived N-Unsubstituted Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520533441024","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rhodium‐Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Allenes by the [3+2] Annulation of Aryl Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521197546112","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Design and Synthesis of Chiral Diene Ligands for Rh<sup>I</sup>‐Catalyzed Enantioselective Arylation of <i>N</i>‐DPP‐protected Aldimines: Synthesis of the Antifungal Agent Bifonazole"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994693899520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pd(II)-Catalyzed Asymmetric Addition of Arylboronic Acids to Isatin-Derived Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994783203200","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent applications of chiral N-tert-butanesulfinyl imines, chiral diene ligands and chiral sulfur–olefin ligands in asymmetric synthesis"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699996070654720","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ni(II)-catalyzed asymmetric alkenylations of ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469959348352","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Rhodium(I)‐Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed CH Activations"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418308043520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Palladium‐Catalyzed Enantioselective Addition of Arylboronic Acids to Cyclic Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418738983936","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Palladium-Catalyzed Enantioselective Synthesis of Cyclic Sulfamidates and Application to a Synthesis of Verubecestat"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420096967936","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Rhodium‐Catalyzed Addition of Arylboroxines to N‐Unprotected Ketimines: Efficient Synthesis of Cipargamin"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894473900288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Enantioselective rhodium-catalyzed arylation of electron-deficient alkenylarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107369787281920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rhodium-Catalyzed Asymmetric Arylation of <i>N</i>-Tosyl Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370241071744","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Synthesis of Axially Chiral 2‐Aminobiaryls by Rhodium‐Catalyzed Benzannulation of 1‐Arylalkynes with 2‐(Cyanomethyl)phenylboronates"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107371228267776","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pd(<scp>ii</scp>), Ni(<scp>ii</scp>) and Co(<scp>ii</scp>)-catalyzed enantioselective additions of organoboron reagents to ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388844132598528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Rh/Pd Catalysis with Chiral and Achiral Ligands: Domino Synthesis of Aza‐Dihydrodibenzoxepines"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845610940928","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefins"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845755550976","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Catalytic diastereo- and enantioselective additions of versatile allyl groups to N–H ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670318374695424","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<i>N</i>-Sulfonyl Bisimidazoline Ligands and Their Applications in Pd(II)-Catalyzed Asymmetric Addition toward α-Tertiary Amines"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670318691165312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Palladium‐Catalyzed Enantioselective Addition of Arylboronic Acids to Cyclic Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319633880576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis of chiral 3-substituted 3-amino-2-oxindoles through enantioselective catalytic nucleophilic additions to isatin imines"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320942620032","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794671207936","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Tertiary Carbinamine Synthesis by Rhodium‐Catalyzed [3+2] Annulation of N‐Unsubstituted Aromatic Ketimines and Alkynes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795301379200","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Synthesis of Axially Chiral 2‐Aminobiaryls by Rhodium‐Catalyzed Benzannulation of 1‐Arylalkynes with 2‐(Cyanomethyl)phenylboronates"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795380596352","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A second-generation ligand for the enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylazaarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233271197819264","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Transition Metal-Catalyzed Asymmetric Addition of Organoboron Reagents to Imines"}]},{"@id":"https://cir.nii.ac.jp/crid/1390572244932057088","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Greener Catalytic Synthetic Methods of Nitrogen-Containing Compounds Using <i>N</i>-Unprotected Ketimines"},{"@language":"ja","@value":"無保護ケチミンを活用した環境調和型新規触媒的含窒素化合物合成手法の開発"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714791998240896","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent advances in catalytic asymmetric C-C bond-forming reactions to ketimines promoted by metal-based catalysts"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/asia.201901745"},{"@type":"KAKEN","@value":"PRODUCT-22931881"},{"@type":"KAKEN","@value":"PRODUCT-23638273"},{"@type":"KAKEN","@value":"PRODUCT-22829390"},{"@type":"KAKEN","@value":"PRODUCT-22993995"},{"@type":"OPENAIRE","@value":"doi_dedup___::1a7966b5ace25d2a0646dac07ac709c1"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20230055_references_DOI_KbC4ydkGShJlr63KQ6CHz4FrDDy"},{"@type":"CROSSREF","@value":"10.1021/acscatal.2c05953_references_DOI_KbC4ydkGShJlr63KQ6CHz4FrDDy"},{"@type":"CROSSREF","@value":"10.1055/a-2131-3448_references_DOI_KbC4ydkGShJlr63KQ6CHz4FrDDy"},{"@type":"CROSSREF","@value":"10.1021/acscatal.0c01212_references_DOI_KbC4ydkGShJlr63KQ6CHz4FrDDy"},{"@type":"CROSSREF","@value":"10.5059/yukigoseikyokaishi.80.2_references_DOI_KbC4ydkGShJlr63KQ6CHz4FrDDy"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.1c01194_references_DOI_KbC4ydkGShJlr63KQ6CHz4FrDDy"},{"@type":"CROSSREF","@value":"10.1007/978-981-16-2458-2_15_references_DOI_KbC4ydkGShJlr63KQ6CHz4FrDDy"}]}