{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361412891759136256.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.fuproc.2019.106182"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0378382019308914?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0378382019308914?httpAccept=text/plain"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Hydroconversion of methyl laurate over beta-zeolite-supported Ni–Mo catalysts: Effect of acid and base treatments of beta zeolite"}],"description":[{"notation":[{"@value":"Abstract   Beta-zeolite-supported Ni–Mo catalysts, NiMo/HBeta, were developed and applied to the hydroconversion of methyl laurate under a hydrogen pressure of 0.4 MPa. Compared with the Ni–Mo catalyst supported on a zeolite with no Al content, NiMo/HBeta exhibited high catalytic activity and selectivity for n-dodecane produced through the hydrodeoxygenation (HDO) process. Furthermore, prior to Ni–Mo particle loading, beta zeolite was acid-treated with HNO3 solution or base-treated with tetraethylammonium hydroxide (TEAOH) or NaOH solutions. The acid and base treatments influenced the Ni–Mo particles, with large Ni–Mo particles formed on the acid-treated beta zeolite and small, highly dispersed Ni–Mo particles formed on the base-treated beta zeolites. Both the acid- and TEAOH-treated beta zeolites improved the catalytic activity and enhanced the HDO process, whereas the NaOH-treated beta zeolite slightly depressed the catalytic activity. An increased ratio of Bronsted acid sites in beta zeolite played an important role in improving both the catalytic activity and the HDO process. The combination of the TEAOH treatment of beta zeolite with subsequent acid treatment was effective for further improving the catalytic activity while maintaining high n-dodecane selectivity."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381412891759136257","@type":"Researcher","foaf:name":[{"@value":"Miku Abe"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326224025984","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70514610"},{"@type":"NRID","@value":"1000070514610"},{"@type":"NRID","@value":"9000413573322"}],"foaf:name":[{"@value":"Hiroyuki Imai"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891759136262","@type":"Researcher","foaf:name":[{"@value":"Hiroshi Yamazaki"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891759136258","@type":"Researcher","foaf:name":[{"@value":"Toshiyuki Yokoi"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891759136259","@type":"Researcher","foaf:name":[{"@value":"Ryota Osuga"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891759136256","@type":"Researcher","foaf:name":[{"@value":"Junko N. Kondo"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891759136261","@type":"Researcher","foaf:name":[{"@value":"Kazusa Terasaka"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03783820"}],"prism:publicationName":[{"@value":"Fuel Processing Technology"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2020-01","prism:volume":"197","prism:startingPage":"106182"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/","https://www.elsevier.com/legal/tdmrep-license"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0378382019308914?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0378382019308914?httpAccept=text/plain"}],"createdAt":"2019-09-03","modifiedAt":"2025-10-08","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782017828864","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"19K05154"},{"@type":"JGN","@value":"JP19K05154"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-19K05154/"}],"notation":[{"@language":"ja","@value":"遷移金属類の単核サイトに基づく新奇な触媒機能を有するゼオライト触媒の創製"},{"@language":"en","@value":"Development of zeolite having specific catalysis provided by transition metal single site"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002215847890304","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydroconversion of fatty acid derivative over supported Ni-Mo catalysts under low hydrogen pressure"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144346560384","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Biodiesel processing and production"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145735818624","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Upgrading of palmitic acid to iso-alkanes over bi-functional Mo/ZSM-22 catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619938223872","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Vegetable Oil to Biolubricants: Review on Advanced Porous Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620970188288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effect of TiO<sub>2</sub> Coating on Morphology of Active Phase on Sulfided CoMo/Al<sub>2</sub>O<sub>3</sub> Hydrotreating Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292621470013184","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567179936227200","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Total Hydrogenation of Furfural over a Silica‐Supported Nickel Catalyst Prepared by the Reduction of a Nickel Nitrate Precursor"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093504719872","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Manipulating Catalytic Pathways: Deoxygenation of Palmitic Acid on Multifunctional Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574094335471232","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent progress on upgrading of bio-oil to hydrocarbons over metal/zeolite bifunctional catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574094709215360","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Conversion of Palmitic Acid Over Bi-functional Ni/ZSM-5 Catalyst: Effect of Stoichiometric Ni/Al Molar Ratio"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095863882240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrocarbon bio-oil production from pyrolysis bio-oil using non-sulfide Ni-Zn/Al2O3 catalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1360845539069325312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Characterization of nickel/silica catalysts during impregnation and further thermal activation treatment leading to metal particles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569224146304","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An infrared study of pyridine adsorbed on acidic solids. 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