{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361412891995360896.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.matdes.2019.108452"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0264127519308901?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0264127519308901?httpAccept=text/plain"}},{"identifier":{"@type":"DOI","@value":"10.2139/ssrn.3411750"}},{"identifier":{"@type":"DOI","@value":"10.48550/arxiv.1906.05176"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Thermodynamic origin of solute-enriched stacking-fault in dilute Mg-Zn-Y alloys"}],"description":[{"notation":[{"@value":"We investigate thermodynamic behaviors of dilute Mg-Zn-Y ternary alloys to form a unique solute-enriched stacking-fault (SESF), which is an intrinsic-II type stacking-fault (I2-SF) enriched by the Zn and Y atoms and represents the structural-unit of the long-period stacking/order (LPSO) phase. SESF in the hexagonal-close-packed (hcp) Mg matrix forms a local face-centered-cubic (fcc) environment, and hence our thermodynamic analysis is based on the Gibbs energy comparison between hcp and fcc phases over the Mg-Zn-Y ternary composition ranges, using the calculation of phase diagrams (CALPHAD) method aided by the first principles calculations. Segregation behaviors of solute Zn/Y atoms into the SESF are firstly estimated according to the Hillert's parallel tangent law, followed by the possible disorder-order phase transformation within the SESF using the multiple-sublattice model. We find that the Zn/Y co-segregations at the SESF provide a remarkable condition that the fcc layers become more stable than the hcp-Mg matrix. Besides, within the SESF, the following spinodal-like decomposition into the Mg-rich solid-solution and the Zn/Y-rich L12-type order phase causes a significant reduction of the total Gibbs energy of the system. These thermodynamic behaviors explain fairly well a phenomenological origin of the Zn-Y clustering with the L12-type short-range order, which is known to occur for the LPSO phases and also confirmed for the present SESF by electron microscopy experiments. Therefore, strong Zn-Y interactions even in dilute conditions play a key role to stabilize firmly the SESF in the Mg-Zn-Y alloys."}]},{"notation":[{"@value":"53 pages, 10 figures, 4 tables; submitted to Acta Materialia"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381412891995360896","@type":"Researcher","foaf:name":[{"@value":"M. Egami"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891995360768","@type":"Researcher","foaf:name":[{"@value":"I. Ohnuma"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891995360897","@type":"Researcher","foaf:name":[{"@value":"M. Enoki"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891995360769","@type":"Researcher","foaf:name":[{"@value":"H. Ohtani"}]},{"@id":"https://cir.nii.ac.jp/crid/1381412891995360898","@type":"Researcher","foaf:name":[{"@value":"E. 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