{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361418520071576832.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/0304-386x(84)90018-5"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:0304386X84900185?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:0304386X84900185?httpAccept=text/plain"}},{"identifier":{"@type":"NAID","@value":"80002191086"}}],"dc:title":[{"@value":"Solvent extraction equilibria of copper and nickel with SME 529"}],"description":[{"notation":[{"@value":"Abstract   Distribution equilibria in the extraction of copper and nickel from 1.0 mol/dm 3  aqueous ammonium nitrate solution by  anti -2-hydroxy-5-nonylacetophenone oxime, the active species of SME 529, in MSB 210 diluent were studied at 30°C. The extraction equilibrium constants for copper and nickel were determined to be 1.9 × 10 1  and 3.2 × 10 5 , respectively. The aqueous solubility of the oxime was also examined, resulting in a measurement of the partition coefficient of the monomeric oxime between the aqueous and organic phases, its dissociation constant in the aqueous phase and its dimerization constant in the organic phase as 2.2 × 10 −4 , 0.53 nmol/dm 3  and 31 dm 3 /mol, respectively. It was found that the extraction of copper is decreased by the addition of  p -nonylphenol due to adduct formation. The equilibrium constant of the adduct formation between the oxime and  p -nonylphenol was determined to be 6.6 dm 3 /mol. It was observed that nickel is extracted by  p -nonylphenol."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381418520071576960","@type":"Researcher","foaf:name":[{"@value":"Katsutoshi Inoue"}]},{"@id":"https://cir.nii.ac.jp/crid/1381418520071576832","@type":"Researcher","foaf:name":[{"@value":"Hiroki Tsunomachi"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"0304386X"}],"prism:publicationName":[{"@value":"Hydrometallurgy"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"1984-10","prism:volume":"13","prism:number":"1","prism:startingPage":"73","prism:endingPage":"87"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:0304386X84900185?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:0304386X84900185?httpAccept=text/plain"}],"createdAt":"2003-08-06","modifiedAt":"2019-03-16","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390001204246373376","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Modeling of Solvent Extraction Equilibria of Cu(II) from Sulfuric Acid Solutions with β-Hydroxyoxime"},{"@value":"Modeling of Solvent Extraction Equilibria of Cu(II) from Sulfuric Acid Solutions with β-Hydroxyoxime"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204247931136","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Application of LIX 84 for Separation of Copper, Nickel and Cobalt in Ammoniacal Leaching of Ocean Nodules"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679489953024","@type":"Article","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Nickel Recycling from Spent Electroless Nickel Plating Baths Using Solvent Extraction"},{"@language":"ja","@value":"溶媒抽出法を用いた使用済み無電解ニッケルめっき液からのニッケルリサイクルに関する研究"},{"@language":"ja-Kana","@value":"ヨウバイ チュウシュツホウ オ モチイタ シヨウズミ ムデンカイ ニッケルメッキ エキ カラ ノ ニッケルリサイクル ニ カンスル ケンキュウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680993673600","@type":"Article","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Separation of the Metals in the Spent Electroless Nickel Plating Baths by Solvent Extraction"},{"@language":"ja","@value":"溶媒抽出法による使用済み無電解ニッケルめっき浴からの金属成分の分離"},{"@language":"ja-Kana","@value":"ヨウバイ チュウシュツホウ ニ ヨル シヨウズミ ムデンカイ ニッケルメッキ ヨク カラ ノ キンゾク セイブン ノ ブンリ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681026813056","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Improvement of the Extraction and Stripping Rates of Nickel in the Solvent Extraction System with LIX84I"},{"@language":"ja","@value":"LIX84Iによるニッケルの溶媒抽出における正および逆抽出速度の改善"},{"@language":"ja-Kana","@value":"LIX84I ニ ヨル ニッケル ノ ヨウバイ チュウシュツ ニ オケル セイ オヨビ ギャクチュウシュツ ソクド ノ カイゼン"}]},{"@id":"https://cir.nii.ac.jp/crid/1570009750704357504","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"IMPROVEMENT OF THE EXTRACTION AND STRIPPING RATES OF NICKEL IN A SOLVENT EXTRACTION SYSTEM WITH LIX84I"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/0304-386x(84)90018-5"},{"@type":"CIA","@value":"80002191086"},{"@type":"OPENAIRE","@value":"doi_dedup___::62833ebcbdebf0ed143b733f0f1dc16c"},{"@type":"CROSSREF","@value":"10.2473/shigentosozai.120.440_references_DOI_ZAeQCzE1eATKSv1MWsugslPMRWd"},{"@type":"CROSSREF","@value":"10.2320/matertrans1989.31.409_references_DOI_ZAeQCzE1eATKSv1MWsugslPMRWd"},{"@type":"CROSSREF","@value":"10.2320/matertrans1989.32.157_references_DOI_ZAeQCzE1eATKSv1MWsugslPMRWd"},{"@type":"CROSSREF","@value":"10.2473/shigentosozai.118.751_references_DOI_ZAeQCzE1eATKSv1MWsugslPMRWd"},{"@type":"CROSSREF","@value":"10.1252/kakoronbunshu.36.201_references_DOI_ZAeQCzE1eATKSv1MWsugslPMRWd"}]}