{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361418520110565504.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ange.201411807"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201411807"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201411807"}}],"dc:title":[{"@value":"Silver‐Mediated Oxidative Aliphatic CH Trifluoromethylthiolation"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The first example of a practical and direct trifluoromethylthiolation reaction of unactivated aliphatic CH bonds employs a silver‐based reagent. The reaction is operationally simple, scalable, and proceeds under aqueous conditions in air. Furthermore, its broad scope and good functional‐group compatibility were demonstrated by applying this method to the selective trifluoromethylthiolation of natural products and natural‐product derivatives.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381418520110565632","@type":"Researcher","foaf:name":[{"@value":"Shuo Guo"}]},{"@id":"https://cir.nii.ac.jp/crid/1381418520110565634","@type":"Researcher","foaf:name":[{"@value":"Xiaofei Zhang"}]},{"@id":"https://cir.nii.ac.jp/crid/1381418520110565633","@type":"Researcher","foaf:name":[{"@value":"Pingping Tang"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00448249"},{"@type":"EISSN","@value":"15213757"}],"prism:publicationName":[{"@value":"Angewandte Chemie"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-02-25","prism:volume":"127","prism:number":"13","prism:startingPage":"4137","prism:endingPage":"4141"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201411807"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201411807"}],"createdAt":"2015-02-25","modifiedAt":"2023-09-14","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390001204142494208","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"},{"@value":"Award Accounts : The Chemical Society of Japan Award for Creative Work for 2014 : Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ange.201411807"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160223_references_DOI_XND7pumktTvsr4SfG27hTHO4lkR"}]}