{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361418520182393472.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/adsc.201500261"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.201500261"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.201500261"}}],"dc:title":[{"@value":"Copper‐Catalyzed Aryltrifluoromethylation of <i>N</i>‐Phenylcinnamamides: Access to Trifluoromethylated 3,4‐Dihydroquinolin‐2(1 <i>H</i>)‐ones"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A method for copper‐catalyzed aryltrifluoromethylation of <jats:italic>N</jats:italic>‐phenylcinnamamides is reported. This method provides a straightforward route to a variety of CF<jats:sub>3</jats:sub>‐containing 3,4‐dihydroquinolin‐2(1 <jats:italic>H</jats:italic>)‐ones with excellent regioselectivity and diastereoselectivity.</jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" mimetype=\"image/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic/mcontent.gif\"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381418520182393475","@type":"Researcher","foaf:name":[{"@value":"Qiang Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1381418520182393474","@type":"Researcher","foaf:name":[{"@value":"Guifang Han"}]},{"@id":"https://cir.nii.ac.jp/crid/1381418520182393473","@type":"Researcher","foaf:name":[{"@value":"Yuxiu Liu"}]},{"@id":"https://cir.nii.ac.jp/crid/1381418520182393472","@type":"Researcher","foaf:name":[{"@value":"Qingmin Wang"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16154150"},{"@type":"EISSN","@value":"16154169"}],"prism:publicationName":[{"@value":"Advanced Synthesis & Catalysis"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-07-23","prism:volume":"357","prism:number":"11","prism:startingPage":"2464","prism:endingPage":"2468"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.201500261"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.201500261"}],"createdAt":"2015-07-23","modifiedAt":"2025-10-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/2050588892096788096","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkylation methods for synthesizing versatile building blocks"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/adsc.201500261"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190080_references_DOI_ZoXsldb9yG1EiFUlyMdSdpk0m7a"}]}