{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361418521245006336.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201409983"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201409983"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201409983"}}],"dc:title":[{"@value":"Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra‐<i>n</i>‐butylammonium Iodide"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>An unprecedented reaction for the direct trifluoromethylthiolation and fluorination of alkyl alcohols using AgSCF<jats:sub>3</jats:sub> and nBu<jats:sub>4</jats:sub>NI has been developed. The trifluoromethylthiolated compounds and alkyl fluorides were selectively formed by changing the ratio of AgSCF<jats:sub>3</jats:sub>/nBu<jats:sub>4</jats:sub>NI. This protocol is tolerant of different functional groups and might be applicable to late‐stage trifluoromethylthiolation of alcohols.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380861291021759875","@type":"Researcher","foaf:name":[{"@value":"Jian‐Bo Liu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861291021759873","@type":"Researcher","foaf:name":[{"@value":"Xiu‐Hua Xu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861291021759872","@type":"Researcher","foaf:name":[{"@value":"Zeng‐Hao Chen"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861291021759874","@type":"Researcher","foaf:name":[{"@value":"Feng‐Ling Qing"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2014-11-24","prism:volume":"54","prism:number":"3","prism:startingPage":"897","prism:endingPage":"900"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201409983"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201409983"}],"createdAt":"2014-11-24","modifiedAt":"2023-10-16","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360580232135516928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Acyl Fluorides from Carboxylic Acids with KI/AgSCF<sub>3</sub> for Efficient Amide and Peptide Synthesis"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204142494208","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"},{"@value":"Award Accounts : The Chemical Society of Japan Award for Creative Work for 2014 : Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201409983"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160223_references_DOI_5RuThbbVsI1Tb15oJMYMvttjo8C"},{"@type":"CROSSREF","@value":"10.1002/adsc.202201103_references_DOI_5RuThbbVsI1Tb15oJMYMvttjo8C"}]}