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We demonstrate the importance of the activating group, attached to the nitrogen, and its specificity for the fluorinated group to be delivered. As an application, a variety of unknown dichlorofluoro, bromodifluoro, and trifluoromethyl alkynes have been prepared using these reagents.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699993780778370","@type":"Researcher","foaf:name":[{"@value":"Céline Urban"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699993780778368","@type":"Researcher","foaf:name":[{"@value":"Frédéric Cadoret"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861290832775936","@type":"Researcher","foaf:name":[{"@value":"Jean‐Claude Blazejewski"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699993780778371","@type":"Researcher","foaf:name":[{"@value":"Emmanuel Magnier"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1434193X"},{"@type":"EISSN","@value":"10990690"}],"prism:publicationName":[{"@value":"European Journal of Organic Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2011-07-11","prism:volume":"2011","prism:number":"25","prism:startingPage":"4862","prism:endingPage":"4867"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201100503"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.201100503"}],"createdAt":"2011-07-11","modifiedAt":"2025-10-15","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004229920419072","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"<i>S</i>‐((Phenylsulfonyl)difluoromethyl)thiophenium Salts: Carbon‐Selective Electrophilic Difluoromethylation of β‐Ketoesters, β‐Diketones, and Dicyanoalkylidenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285705221938048","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri‐, Di‐ and Monofluoromethylations of β‐Ketoesters"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708539670656","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Asymmetric synthesis of chiral trifluoromethylated heliotridane via highly catalytic asymmetric Friedel–Crafts alkylation with β-trifluoromethylated acrylates and pyrroles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302866830686208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkyl Sulfoximines for Versatile Photocatalytic Radical Fluoroalkylations"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565164584627200","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Efficient Difluoromethylation of sp<sup>3</sup> Carbon Nucleophiles by Bromodifluoromethylation Reagents with Organic Bases"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166589000960","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthetic Methods for Compounds Having CF<sub>3</sub>–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658179662720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selective<i>O</i>-Difluoromethylation of 1,3-Diones by Bromodifluoromethylating Reagents"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204142494208","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"},{"@value":"Award Accounts : The Chemical Society of Japan Award for Creative Work for 2014 : Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ejoc.201100503"},{"@type":"CROSSREF","@value":"10.1002/anie.201309875_references_DOI_PK3fNRa3EI7navOcxAnsHR7u3J7"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160223_references_DOI_PK3fNRa3EI7navOcxAnsHR7u3J7"},{"@type":"CROSSREF","@value":"10.1002/open.201200032_references_DOI_PK3fNRa3EI7navOcxAnsHR7u3J7"},{"@type":"CROSSREF","@value":"10.1002/open.201200033_references_DOI_PK3fNRa3EI7navOcxAnsHR7u3J7"},{"@type":"CROSSREF","@value":"10.1021/cr500193b_references_DOI_PK3fNRa3EI7navOcxAnsHR7u3J7"},{"@type":"CROSSREF","@value":"10.1021/ol4000313_references_DOI_PK3fNRa3EI7navOcxAnsHR7u3J7"},{"@type":"CROSSREF","@value":"10.1002/tcr.202300032_references_DOI_PK3fNRa3EI7navOcxAnsHR7u3J7"},{"@type":"CROSSREF","@value":"10.1039/c1nj20550a_references_DOI_PK3fNRa3EI7navOcxAnsHR7u3J7"}]}