{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699994196107136.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/chem.200802534"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.200802534"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.200802534"}}],"dc:title":[{"@value":"Dual Organocatalysis: Asymmetric Allylic–Allylic Alkylation of α,α‐Dicyanoalkenes and Morita–Baylis–Hillman Carbonates"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p><jats:bold>The first highly enantioselective allylic–allylic alkylation</jats:bold> of α,α‐dicyanoalkenes and Morita–Baylis–Hillman carbonates by dual catalysis of (DHQD)<jats:sub>2</jats:sub>AQN and (<jats:italic>S</jats:italic>)‐BINOL has been investigated. Excellent stereoselectivities have been achieved for a broad spectrum of substrates (d.r. > 99:1, up to 99 % <jats:italic>ee</jats:italic>). The multifunctional allylic products could be efficiently converted to a range of complex chiral cyclic frameworks. EWG=electron‐withdrawing group, (DHQD)<jats:sub>2</jats:sub>AQN=hydroquinidine (anthraquinone‐1,4‐diyl) diether, (<jats:italic>S</jats:italic>)‐BINOL =(<jats:italic>S</jats:italic>)‐(−)‐1,1′‐bi‐2‐naphthol.<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" mimetype=\"image/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic/mcontent.gif\"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p><jats:p>No Abstract</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380298343072616705","@type":"Researcher","foaf:name":[{"@value":"Hai‐Lei Cui"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994196107136","@type":"Researcher","foaf:name":[{"@value":"Jing Peng"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994196107138","@type":"Researcher","foaf:name":[{"@value":"Xin Feng"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994196107140","@type":"Researcher","foaf:name":[{"@value":"Wei Du"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994196107137","@type":"Researcher","foaf:name":[{"@value":"Kun Jiang"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298343072616704","@type":"Researcher","foaf:name":[{"@value":"Ying‐Chun Chen"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09476539"},{"@type":"EISSN","@value":"15213765"}],"prism:publicationName":[{"@value":"Chemistry – A European Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2009-01-26","prism:volume":"15","prism:number":"7","prism:startingPage":"1574","prism:endingPage":"1577"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.200802534"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.200802534"}],"createdAt":"2009-01-08","modifiedAt":"2025-10-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233249287424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Organocatalyzed Regio- and Enantioselective Allylic Trifluoromethylation of Morita–Baylis–Hillman Adducts Using Ruppert–Prakash Reagent"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144781821824","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Allylic Monofluoromethylation and Methylation of Morita–Baylis–Hillman Carbonates with FBSM and BSM by Cooperative Cinchona Alkaloid/FeCl<sub>2</sub> Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183166835584","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cinchona Alkaloid Amides/Dialkylzinc Catalyzed Enantioselective Desymmetrization of Aziridines with Phosphites"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/chem.200802534"},{"@type":"CROSSREF","@value":"10.1002/anie.201103748_references_DOI_RAiaszD0XE3Fmmdlc2EzuJsjPCH"},{"@type":"CROSSREF","@value":"10.1021/ja309963w_references_DOI_RAiaszD0XE3Fmmdlc2EzuJsjPCH"},{"@type":"CROSSREF","@value":"10.1021/ol201490e_references_DOI_RAiaszD0XE3Fmmdlc2EzuJsjPCH"}]}