{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699994295854848.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1038/ncomms15377"}},{"identifier":{"@type":"URI","@value":"https://www.nature.com/articles/ncomms15377.pdf"}},{"identifier":{"@type":"URI","@value":"https://www.nature.com/articles/ncomms15377"}},{"identifier":{"@type":"URI","@value":"http://www.nature.com/doifinder/10.1038/ncomms15377"}}],"dc:title":[{"@value":"Amorphous nickel-cobalt complexes hybridized with 1T-phase molybdenum disulfide via hydrazine-induced phase transformation for water splitting"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Highly active and robust eletcrocatalysts based on earth-abundant elements are desirable to generate hydrogen and oxygen as fuels from water sustainably to replace noble metal materials. Here we report an approach to synthesize porous hybrid nanostructures combining amorphous nickel-cobalt complexes with 1T phase molybdenum disulfide (MoS<jats:sub>2</jats:sub>) via hydrazine-induced phase transformation for water splitting. The hybrid nanostructures exhibit overpotentials of 70 mV for hydrogen evolution and 235 mV for oxygen evolution at 10 mA cm<jats:sup>−2</jats:sup> with long-term stability, which have superior kinetics for hydrogen- and oxygen-evolution with Tafel slope values of 38.1 and 45.7 mV dec<jats:sup>−1</jats:sup>. Moreover, we achieve 10 mA cm<jats:sup>−2</jats:sup> at a low voltage of 1.44 V for 48 h in basic media for overall water splitting. We propose that such performance is likely due to the complete transformation of MoS<jats:sub>2</jats:sub> to metallic 1T phase, high porosity and stabilization effect of nickel-cobalt complexes on 1T phase MoS<jats:sub>2</jats:sub>.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699994295854721","@type":"Researcher","foaf:name":[{"@value":"Haoyi Li"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994295854850","@type":"Researcher","foaf:name":[{"@value":"Shuangming Chen"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994295854720","@type":"Researcher","foaf:name":[{"@value":"Xiaofan Jia"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994295854849","@type":"Researcher","foaf:name":[{"@value":"Biao Xu"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994295854722","@type":"Researcher","foaf:name":[{"@value":"Haifeng Lin"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994295854851","@type":"Researcher","foaf:name":[{"@value":"Haozhou Yang"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994295854852","@type":"Researcher","foaf:name":[{"@value":"Li Song"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994295854848","@type":"Researcher","foaf:name":[{"@value":"Xun Wang"}]}],"publication":{"publicationIdentifier":[{"@type":"EISSN","@value":"20411723"}],"prism:publicationName":[{"@value":"Nature Communications"}],"dc:publisher":[{"@value":"Springer Science and Business Media LLC"}],"prism:publicationDate":"2017-05-09","prism:volume":"8","prism:number":"1","prism:startingPage":"15377"},"reviewed":"false","dc:rights":["https://creativecommons.org/licenses/by/4.0","https://creativecommons.org/licenses/by/4.0"],"url":[{"@id":"https://www.nature.com/articles/ncomms15377.pdf"},{"@id":"https://www.nature.com/articles/ncomms15377"},{"@id":"http://www.nature.com/doifinder/10.1038/ncomms15377"}],"createdAt":"2017-05-09","modifiedAt":"2022-12-23","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004232267989248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Recent progress in functionalized layered double hydroxides and their application in efficient electrocatalytic water oxidation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360286992984620544","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Interface Modulation of Two-Dimensional Superlattices for Efficient Overall Water Splitting"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694364739378944","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Amorphous Catalysts and Electrochemical Water Splitting: An Untold Story of Harmony"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1038/ncomms15377"},{"@type":"CROSSREF","@value":"10.1016/j.jechem.2018.07.007_references_DOI_8ZNpRsBpNwAGnYZkR9yAUv7wqOw"},{"@type":"CROSSREF","@value":"10.1002/smll.201905779_references_DOI_8ZNpRsBpNwAGnYZkR9yAUv7wqOw"},{"@type":"CROSSREF","@value":"10.1021/acs.nanolett.9b01329_references_DOI_8ZNpRsBpNwAGnYZkR9yAUv7wqOw"}]}