{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699994395635712.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.464819"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/98/8/6257/19285882/6257_1_online.pdf"}}],"dc:title":[{"@value":"Translational diffusion of a transient radical studied by the transient grating method, pyrazinyl radical in 2-propanol"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>A translational diffusion coefficient (Ddiff) of a transient radical created by a photochemical reaction of pyrazine in 2-propanol is measured by the transient grating technique. The rise and decay curves of the transient grating signal on the millisecond time scale are attributed to the diffusion of the pyrazinyl radical and the parent molecule (pyrazine). Ddiff of both species are determined. The measured Ddiff of the radical is four times smaller than that of pyrazine even though the molecular size is similar to each other. The small Ddiff suggests that the radical–solvent interaction is stronger than the parent molecule–solvent interaction.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699994395635712","@type":"Researcher","foaf:name":[{"@value":"Masahide Terazima"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Faculty of Science, Kyoto University, Kyoto, 606, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994395635713","@type":"Researcher","foaf:name":[{"@value":"Noboru Hirota"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Faculty of Science, Kyoto University, Kyoto, 606, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"1993-04-15","prism:volume":"98","prism:number":"8","prism:startingPage":"6257","prism:endingPage":"6262"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/98/8/6257/19285882/6257_1_online.pdf"}],"createdAt":"2002-07-26","modifiedAt":"2024-02-07","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050282810694946432","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Light-Induced Conformational Change and Transient Dissociation Reaction of the BLUF Photoreceptor Synechocystis PixD (Slr1694)."}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219104188928","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Diffusion Process of a Liquid Crystal Probed by the Transient Grating Method"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004232146599680","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A way to sense light intensity: Multiple-excitation of the BLUF photoreceptor TePixD suppresses conformational change"}]},{"@id":"https://cir.nii.ac.jp/crid/1360013168887809152","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A Time-Resolved Diffusion Technique for Detection of the Conformational Changes and Molecular Assembly/Disassembly Processes of Biomolecules"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708189619712","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Transient Dissociation of the Transducer Protein from Anabaena Sensory Rhodopsin Concomitant with Formation of the M State Produced upon Photoactivation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360294643775813504","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Size evaluation of gold nanoparticles using transient grating method with deep-UV excitation pulses"}]},{"@id":"https://cir.nii.ac.jp/crid/1360294643863926528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Spectrally Silent Protein Reaction Dynamics Revealed by Time-Resolved Thermodynamics and Diffusion Techniques"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298337088169856","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular diffusion and aggregate formation of photoproducts from ketoprofen in aqueous solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567182268312320","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ultrafast photon echo experiments in condensed phase: Detection of solvation dynamics, coherent wavepacket motions and static inhomogeneity"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644035131904","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Time-Resolved Thermodynamic Properties of Intermediate Species during Photochemical Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360861704771471232","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Applications of Time-Resolved Thermodynamics for Studies on Protein Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360861705563875840","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Revealing protein reactions using transient grating method: Photo-induced heating, volume change, and diffusion change"}]},{"@id":"https://cir.nii.ac.jp/crid/1361975841614652032","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Spiropyran labeling for sensitive probing of protein diffusion by the transient grating method"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679359309696","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Local Density Effect on the Diffusion of the Reaction Intermediate Radicals"},{"@language":"ja","@value":"超臨界流体の拡散と反応　　反応中間体ラジカルの拡散からみた局所密度効果"},{"@value":"反応中間体ラジカルの拡散からみた局所密度効果"},{"@language":"ja-Kana","@value":"ハンノウ チュウカンタイ ラジカル ノ カクサン カラ ミタ キョクショ ミツド コウカ"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892098136832","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Observation of translational diffusion in a planer supported lipid bilayer membrane by total internal reflection-transient grating method"}]},{"@id":"https://cir.nii.ac.jp/crid/2051151842062066944","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Study on the translational diffusion of transient species in 1-alkyl-3-methylimidazolium-based ionic liquids by transient grating spectroscopy"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1063/1.464819"},{"@type":"OPENAIRE","@value":"doi_dedup___::e3df2c73e23bd6724c7102220e79b5c4"},{"@type":"CROSSREF","@value":"10.1016/j.febslet.2011.02.003_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1246/bcsj.77.23_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.4131/jshpreview.14.12_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.3389/fgene.2021.691010_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1016/j.jmb.2011.04.032_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1016/j.jphotochemrev.2011.05.006_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1016/j.cplett.2021.138763_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1021/acs.accounts.1c00113_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1016/j.cplett.2022.139511_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1246/bcsj.68.2809_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20220099_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20200019_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1016/j.cplett.2019.136919_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.3390/j5010014_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1063/5.0087049_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"},{"@type":"CROSSREF","@value":"10.1021/ja202329u_references_DOI_VbUe7KKz3HjE434EoDfpHxJypay"}]}