{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699994541019392.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/nn101036v"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/nn101036v"}},{"identifier":{"@type":"PMID","@value":"20863104"}}],"dc:title":[{"@value":"Molecular Beam Deposition of Nanoscale Ionic Liquids in Ultrahigh Vacuum"}],"description":[{"notation":[{"@value":"We propose a new approach to nanoscience and technology for ionic liquids (ILs): molecular beam deposition of IL in ultrahigh vacuum by using a continuous wave infrared (CW-IR) laser deposition technique. This approach has made it possible to prepare a variety of \"nano-IL\" with the given composition on the substrate: a nanodroplet, on one hand, the volume of which goes down to 1 aL and, on the other hand, an ultrathin film with a thickness to several 100 nm or less. The result of fractional distillation of a binary mixture of ILs, investigated by nuclear magnetic resonance as well as electrospray ionization time-of-flight mass spectrometry, indicates that this deposition process is based on the thermal evaporation of ILs, and thus this process also can be used as a new purification method of ILs in vacuum. Furthermore, the fabrication of binary mixture droplets of two ILs on the substrate by alternating deposition of two ILs was demonstrated; the homogeneity of the composition was confirmed even for one single droplet by high-spatial-resolution Raman spectroscopy."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699994541019393","@type":"Researcher","foaf:name":[{"@value":"Shingo Maruyama"}],"jpcoar:affiliationName":[{"@value":"Materials and Structures Laboratory"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994541019396","@type":"Researcher","foaf:name":[{"@value":"Yoko Takeyama"}],"jpcoar:affiliationName":[{"@value":"Materials and Structures Laboratory"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994541019395","@type":"Researcher","foaf:name":[{"@value":"Hiroki Taniguchi"}],"jpcoar:affiliationName":[{"@value":"Materials and Structures Laboratory"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994541019392","@type":"Researcher","foaf:name":[{"@value":"Hiroki Fukumoto"}],"jpcoar:affiliationName":[{"@value":"Chemical Resources Laboratory"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994541019400","@type":"Researcher","foaf:name":[{"@value":"Mitsuru Itoh"}],"jpcoar:affiliationName":[{"@value":"Materials and Structures Laboratory"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994541019398","@type":"Researcher","foaf:name":[{"@value":"Hiroshi Kumigashira"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry and JST-CREST, University of Tokyo, Bunkyo-ku, Tokyo 113-8656, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994541019394","@type":"Researcher","foaf:name":[{"@value":"Masaharu Oshima"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry and JST-CREST, University of Tokyo, Bunkyo-ku, Tokyo 113-8656, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994541019397","@type":"Researcher","foaf:name":[{"@value":"Takakazu Yamamoto"}],"jpcoar:affiliationName":[{"@value":"Chemical Resources Laboratory"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994541019399","@type":"Researcher","foaf:name":[{"@value":"Yuji Matsumoto"}],"jpcoar:affiliationName":[{"@value":"Materials and Structures Laboratory"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"19360851"},{"@type":"EISSN","@value":"1936086X"}],"prism:publicationName":[{"@value":"ACS Nano"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2010-09-23","prism:volume":"4","prism:number":"10","prism:startingPage":"5946","prism:endingPage":"5952"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/nn101036v"}],"createdAt":"2010-09-23","modifiedAt":"2024-03-30","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360003449882843136","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ionic liquid-assisted vapor deposition and polymorphs control of 2,2′:5′,2″-terthiophene 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