{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699994702319616.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.469684"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/103/6/2092/8104842/2092_1_online.pdf"}}],"dc:title":[{"@value":"Competition between energy and phase relaxation in electronic curve crossing processes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>We present results from simulations of vibrational energy and phase relaxation and electronic curve crossing using a multilevel formulation of Redfield theory, which demonstrate the shortcomings of the optical Bloch approximation and the importance of coherence transfer processes in the relaxation dynamics of multilevel systems. Specifically, we show that for a harmonic well, energy relaxation can occur with retention of vibrational phase, and that for sufficiently strong electronic coupling, the product of an electronic curve crossing process can be formed vibrationally coherent even when no coherence is present in the initially excited state.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699994702319616","@type":"Researcher","foaf:name":[{"@value":"John M. Jean"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Washington University, St. Louis, Missouri 63130"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994702319617","@type":"Researcher","foaf:name":[{"@value":"Graham R. Fleming"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and The James Franck Institute, University of Chicago, Chicago, Illinois 60637"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"1995-08-08","prism:volume":"103","prism:number":"6","prism:startingPage":"2092","prism:endingPage":"2101"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/103/6/2092/8104842/2092_1_online.pdf"}],"createdAt":"2002-07-26","modifiedAt":"2023-07-09","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002217106317824","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Effect of high-frequency modes on singlet fission dynamics"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004232084446080","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285709968104960","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Phase analysis of coherent radial-breathing-mode phonons in carbon nanotubes: Implications for generation and detection processes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360290617752286080","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Probing excited-state dynamics with quantum entangled photons: Correspondence to coherent multidimensional spectroscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644026931584","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Transition State in a Prevented Proton Transfer Observed in Real Time"}]},{"@id":"https://cir.nii.ac.jp/crid/1521980704682237440","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Award Accounts : The Chemical Society of Japan Award for Young Chemists for 2014 : Development of Novel Reactions Induced by Coherent Molecular Vibrational Excitation and Direct Observation of Molecular Structural Change during \"Thermal\" Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1063/1.469684"},{"@type":"CROSSREF","@value":"10.1063/1.4973981_references_DOI_Vd8N0yRfTIw7opHAjQXJBbluUDx"},{"@type":"CROSSREF","@value":"10.1103/physrevb.97.035441_references_DOI_Vd8N0yRfTIw7opHAjQXJBbluUDx"},{"@type":"CROSSREF","@value":"10.1063/5.0015432_references_DOI_Vd8N0yRfTIw7opHAjQXJBbluUDx"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20100269_references_DOI_Vd8N0yRfTIw7opHAjQXJBbluUDx"},{"@type":"CROSSREF","@value":"10.1016/j.cplett.2012.01.024_references_DOI_Vd8N0yRfTIw7opHAjQXJBbluUDx"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20150242_references_DOI_Vd8N0yRfTIw7opHAjQXJBbluUDx"}]}