{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699994719481344.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ejoc.200800419"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.200800419"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.200800419"}},{"identifier":{"@type":"DOI","@value":"10.1002/chin.200842035"}}],"dc:title":[{"@value":"Fluorinated Johnson Reagent for Transfer‐Trifluoromethylation to Carbon Nucleophiles"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A novel reagent, [(oxido)phenyl(trifluoromethyl)‐λ<jats:sup>4</jats:sup>‐sulfanylidene]dimethylammonium tetrafluoroborate has been developed for the electrophilic trifluoromethylation of carbon nucleophiles. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent. The firstexample of vinylogous trifluoromethylation of dicyanoalkylidenes is also demonstrated.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699994719481347","@type":"Researcher","foaf:name":[{"@value":"Shun Noritake"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994719481348","@type":"Researcher","foaf:name":[{"@value":"Norio Shibata"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994719481346","@type":"Researcher","foaf:name":[{"@value":"Shuichi Nakamura"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994719481345","@type":"Researcher","foaf:name":[{"@value":"Takeshi Toru"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994719481344","@type":"Researcher","foaf:name":[{"@value":"Motoo Shiro"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1434193X"},{"@type":"EISSN","@value":"10990690"}],"prism:publicationName":[{"@value":"European Journal of Organic Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2008-06-23","prism:volume":"2008","prism:number":"20","prism:startingPage":"3465","prism:endingPage":"3468"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.200800419"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.200800419"}],"createdAt":"2008-05-29","modifiedAt":"2025-10-15","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002214424580096","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Combining Photoredox‐Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of α‐Trifluoromethylated Ketones from Aromatic Alkenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216881968512","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A sterically demanding organo-superbase avoids decomposition of a naked trifluoromethyl carbanion directly generated from fluoroform"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004229920419072","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"<i>S</i>‐((Phenylsulfonyl)difluoromethyl)thiophenium Salts: Carbon‐Selective Electrophilic Difluoromethylation of β‐Ketoesters, β‐Diketones, and Dicyanoalkylidenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233249272448","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cu-Mediated Chemoselective Trifluoromethylation of Benzyl Bromides Using Shelf-Stable Electrophilic Trifluoromethylating Reagents"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004239641976576","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Regioselective 1,4-trifluoromethylation of α,β-unsaturated ketones via a <i>S</i>-(trifluoromethyl)diphenylsulfonium salts/copper system"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285705221938048","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri‐, Di‐ and Monofluoromethylations of β‐Ketoesters"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302866830686208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkyl Sulfoximines for Versatile Photocatalytic Radical Fluoroalkylations"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565164376692224","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Inherent Oxygen Preference in Enolate Monofluoromethylation and a Synthetic Entry to Monofluoromethyl Ethers"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565164376884864","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Trifluoromethylation of Aromatic Isoxazoles: Regio‐ and Diastereoselective Route to 5‐Trifluoromethyl‐2‐isoxazolines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565164584627200","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Efficient Difluoromethylation of sp<sup>3</sup> Carbon Nucleophiles by Bromodifluoromethylation Reagents with Organic Bases"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166589000960","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthetic Methods for Compounds Having CF<sub>3</sub>–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567180054752256","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A New Synthetic Approach to Efavirenz through Enantioselective Trifluoromethylation by Using the Ruppert–Prakash Reagent"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658179662720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selective<i>O</i>-Difluoromethylation of 1,3-Diones by Bromodifluoromethylating Reagents"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204142494208","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"},{"@value":"Award Accounts : The Chemical Society of Japan Award for Creative Work for 2014 : Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1882272492578384896","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 699675: Experimental Crystal Structure Determination"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ejoc.200800419"},{"@type":"OPENAIRE","@value":"doi_dedup___::82a2a7cb0a31acbe7f90ccd2c4914828"},{"@type":"CROSSREF","@value":"10.1002/anie.201403590_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1039/c3ob27368g_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1002/anie.201309875_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.3762/bjoc.9.257_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1021/ol201205t_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1002/open.201200032_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160223_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1002/tcr.202300032_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1002/anie.201006218_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1002/anie.201102442_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1002/open.201200033_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1002/ejoc.201101038_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1021/cr500193b_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"},{"@type":"CROSSREF","@value":"10.1021/ol4000313_references_DOI_AQzVRZ9SrnUnEVL8UFH8ZGeAcju"}]}