{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699994903999744.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.200904306"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.200904306"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.200904306"}}],"dc:title":[{"@value":"Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Monocoordinated palladium catalysts derived from sterically hindered, electron‐rich phosphines or N‐heterocyclic carbenes have revolutionized the Suzuki–Miyaura coupling reaction. The emergence of organotrifluoroborates has provided important new perspectives for the organoboron component of these reactions. In combination, these two components prove to be extraordinarily powerful partners for cross‐coupling reactions.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380579819646045056","@type":"Researcher","foaf:name":[{"@value":"Gary A. Molander"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699994903999745","@type":"Researcher","foaf:name":[{"@value":"Belgin Canturk"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2009-11-17","prism:volume":"48","prism:number":"49","prism:startingPage":"9240","prism:endingPage":"9261"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.200904306"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.200904306"}],"createdAt":"2009-11-06","modifiedAt":"2023-10-17","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050022543172265984","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Catalytic Approaches to the Halogen Dance Reaction for Molecular Editing"}]},{"@id":"https://cir.nii.ac.jp/crid/1050306506451325056","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Polystyrene-Supported PPh(3)in Monolithic Porous Material : Effect of Cross-Linking Degree on Coordination Mode and Catalytic Activity in Pd-Catalyzed C-C Cross-Coupling of Aryl Chlorides"},{"@value":"Polystyrene‐Supported PPh<sub>3</sub> in Monolithic Porous Material: Effect of Cross‐Linking Degree on Coordination Mode and Catalytic Activity in Pd‐Catalyzed C−C Cross‐Coupling of Aryl Chlorides"},{"@value":"Polystyrene-Supported PPh3 in Monolithic Porous Material: Effect of Cross-Linking Degree on Coordination Mode and Catalytic Activity in Pd-Catalyzed C−C Cross-Coupling of Aryl Chlorides"}]},{"@id":"https://cir.nii.ac.jp/crid/1050866492739884416","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Ultrafast Halogen Dance Reactions of Bromoarenes Enabled by Catalytic Potassium Hexamethyldisilazide"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002214424340480","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Threefold Cross‐Linked Polystyrene–Triphenylphosphane Hybrids: Mono‐P‐Ligating Behavior and Catalytic Applications for Aryl Chloride Cross‐Coupling and C(sp<sup>3</sup>)H Borylation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216899587456","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Preparation and catalytic performance of a molecularly imprinted Pd complex catalyst for Suzuki cross-coupling reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219111474944","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Pd(II)-catalyzed Cross-coupling of C(sp2)–H Bonds and Alkyl–, Aryl–, and Vinyl–Boron Reagents via Pd(II)/Pd(0) Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002219111587840","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cross-coupling Reactions of Organoboranes: An Easy Method for C–C Bonding"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017282188957568","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Lithium Aryltrifluoroborate as a Catalyst for Halogen Transfer"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283689442481664","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Flash Generation of a Highly Reactive Pd Catalyst for Suzuki–Miyaura Coupling by Using a Flow Microreactor"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691854714624","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708228638464","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Cyclic Alkenylborates via Silaboration of Alkynes Followed by Hydrolysis for Utilization in External-Base-Free Cross Coupling"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166635354112","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Rhodium-Catalyzed Asymmetric Addition of Potassium Organotrifluoroborates to <i>N</i>-Sulfonyl Ketimines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567179848072576","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Robust Palladium‐Catalyzed Arylation of Catalyst‐Poisoning <i>ortho</i>‐Sulfanyl Aryl Halides with Tetraarylborates and Its Application to Synthesis of π‐Extended Dibenzothiophenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567179944011392","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Tripod Immobilization of Triphenylphosphane on a Silica‐Gel Surface to Enable Selective Mono‐Ligation to Palladium: Application to Suzuki–Miyaura Cross‐Coupling Reactions with Chloroarenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360568464518342784","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Copper‐Catalyzed Electrophilic Amidation of Organotrifluoroborates with Use of <i>N</i>‐Methoxyamides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092841265664","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Alkynyl−B(dan)s in Various Palladium‐Catalyzed Carbon−Carbon Bond‐Forming Reactions Leading to Internal Alkynes, 1,4‐Enynes, Ynones, and Multiply Substituted Alkenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572184441598848","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Suzuki–Miyaura Coupling Reactions Using Low Loading of Ligand-activated Palladium Catalyst by Cooperative Copper Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641612253184","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ether-Imidazolium Carbenes for Suzuki–Miyaura Cross-Coupling of Heteroaryl Chlorides with Aryl/Heteroarylboron Reagents"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644035913088","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Highly Efficient Palladium-catalyzed Suzuki–Miyaura Cross-coupling with 9,10-Dihydro-9,10-ethanoanthracene-11,12-diimine Ligands under Mild Aerobic Conditions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644036095104","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Highly Active Palladium Catalysts with Bisacetylacetonate Ligands for Suzuki–Miyaura Cross-coupling Reactions in Mild Conditions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644041701632","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Direct Conversion of Pinacol Arylboronic Esters to Aryl Triolborates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658160059648","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"An Active, General, and Long-Lived Palladium Catalyst for Cross-Couplings of Deactivated (Hetero)aryl Chlorides and Bromides with Arylboronic Acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658160154112","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Palladium-Catalyzed Synthesis of Heterocycle-Containing Diarylmethanes through Suzuki–Miyaura Cross-Coupling"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.200904306"},{"@type":"CROSSREF","@value":"10.1002/anie.201306769_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1039/c7dt00124j_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1002/cctc.202000651_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1021/acscatal.2c06082_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1002/cctc.202400408_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1002/chem.201201579_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1039/c2sc21506c_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1021/ol4010189_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1002/ajoc.201700323_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1002/chem.201304081_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1002/chem.201901145_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1021/ol200958q_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1002/adsc.201801527_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1246/cl.180185_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1002/chem.202400104_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1246/cl.2011.702_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1021/om400138u_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1246/cl.2011.1004_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1021/jo5009178_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1021/jo402089r_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1246/cl.2011.894_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1246/cl.160057_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"},{"@type":"CROSSREF","@value":"10.1246/cl.170705_references_DOI_TyYDlOEjvYj7UVNZWKUVDgDa3HJ"}]}