{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699995622992256.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201708037"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201708037"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201708037"}}],"dc:title":[{"@value":"Alkynylation of C(O)–H Bonds Enabled by Photoredox‐Mediated Hydrogen‐Atom Transfer"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The development of new hydrogen‐atom transfer (HAT) strategies within the framework of photoredox catalysis is highly appealing for its power to activate a desired C−H bond in the substrate leading to its selective functionalization. Reported here is the first photoredox‐mediated hydrogen‐atom transfer method for the efficient synthesis of ynones, ynamides, and ynoates with high regio‐ and chemoselectivity by direct functionalization of C<jats:inline-graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"graphic/anie201708037-math-0002.png\" xlink:title=\"urn:x-wiley:14337851:media:anie201708037:anie201708037-math-0002\"/>\n(O)−H bonds. The broad synthetic application of this method has been demonstrated by the selective functionalization of C(O)−H bonds within complex molecular scaffolds.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699995622992258","@type":"Researcher","foaf:name":[{"@value":"Satobhisha Mukherjee"}],"jpcoar:affiliationName":[{"@value":"Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster  Corrensstrasse 40 48149 Münster Germany"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861290762358912","@type":"Researcher","foaf:name":[{"@value":"R. Aleyda Garza‐Sanchez"}],"jpcoar:affiliationName":[{"@value":"Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster  Corrensstrasse 40 48149 Münster Germany"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861290762358913","@type":"Researcher","foaf:name":[{"@value":"Adrian Tlahuext‐Aca"}],"jpcoar:affiliationName":[{"@value":"Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster  Corrensstrasse 40 48149 Münster Germany"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699995622992256","@type":"Researcher","foaf:name":[{"@value":"Frank Glorius"}],"jpcoar:affiliationName":[{"@value":"Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster  Corrensstrasse 40 48149 Münster Germany"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2017-10-11","prism:volume":"56","prism:number":"46","prism:startingPage":"14723","prism:endingPage":"14726"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201708037"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201708037"}],"createdAt":"2017-09-20","modifiedAt":"2023-09-17","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283689402939520","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synergistic N‐Heterocyclic Carbene/Palladium‐Catalyzed Reactions of Aldehyde Acyl Anions with either Diarylmethyl or Allylic Carbonates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691589729152","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Acceptorless Dehydrogenation of Hydrocarbons by Noble-Metal-Free Hybrid Catalyst System"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285704972926336","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"C(sp<sup>3</sup>)−H Cyanation Promoted by Visible‐Light Photoredox/Phosphate Hybrid Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567007965014912","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Practical Synthesis of α,β-Alkynyl Ketones by Oxidative Alkynylation of Aldehydes with Hypervalent Alkynyliodine Reagents"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183171014528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"<i>N</i>-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092860300672","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Practical Synthesis of 2-Iodosobenzoic Acid (IBA) without Contamination by Hazardous 2-Iodoxybenzoic Acid (IBX) under Mild Conditions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865815482628096","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electrochemical C(sp<sup>3</sup>)−H Functionalization Using Acetic Acid as a Hydrogen Atom Transfer Reagent"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865815493733248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Photocatalytic Aldehyde C−H Bond Phosphonioethylation with Vinylphosphonium Bromide"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201708037"},{"@type":"CROSSREF","@value":"10.1002/anie.201712811_references_DOI_ZWSaz9IICAO7XlswCoHfq6Tg4Vp"},{"@type":"CROSSREF","@value":"10.1002/chem.201801746_references_DOI_ZWSaz9IICAO7XlswCoHfq6Tg4Vp"},{"@type":"CROSSREF","@value":"10.1021/jacs.9b00880_references_DOI_ZWSaz9IICAO7XlswCoHfq6Tg4Vp"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.8b00583_references_DOI_ZWSaz9IICAO7XlswCoHfq6Tg4Vp"},{"@type":"CROSSREF","@value":"10.3390/molecules26071897_references_DOI_ZWSaz9IICAO7XlswCoHfq6Tg4Vp"},{"@type":"CROSSREF","@value":"10.1002/celc.202400061_references_DOI_ZWSaz9IICAO7XlswCoHfq6Tg4Vp"},{"@type":"CROSSREF","@value":"10.1002/ajoc.202300532_references_DOI_ZWSaz9IICAO7XlswCoHfq6Tg4Vp"},{"@type":"CROSSREF","@value":"10.1246/cl.200131_references_DOI_ZWSaz9IICAO7XlswCoHfq6Tg4Vp"}]}