{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699995872233984.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1080/10610278.2010.514915"}},{"identifier":{"@type":"URI","@value":"https://www.tandfonline.com/doi/pdf/10.1080/10610278.2010.514915"}}],"dc:title":[{"@value":"Designing strategies for supramolecular luminescent complex of lanthanide–heterometal assembly"}],"description":[{"notation":[{"@value":"Luminescent complexes consisting of lanthanide, heterometal and ligands can provide supramolecular functions such as extended luminescent lifetime, near-infrared emission and sensing, which result from the heterometal assembly and cannot be realised with a lanthanide homonuclear complex. In this article, kinetic and thermodynamic strategies to construct such supramolecular complexes are reviewed. The kinetic strategy owes to the kinetic inertness of the intermediary homonuclear complex, but allows use of a wide variety of di- or multitopic ligands including relatively simple ones. On the other hand, the ligand used in the thermodynamic strategy so far has been designed with covalent joining of the selective binding sites as exemplified by the highly sophisticated triple-helical complexes. With the view of avoiding elaborate synthesis of ligands in the thermodynamic strategy, supramolecular functional complexes consisting of thiacalixarene, AgI and lanthanide are described, suggesting the possibility of a ..."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699995872233984","@type":"Researcher","foaf:name":[{"@value":"Nobuhiko Iki"}],"jpcoar:affiliationName":[{"@value":"a  Graduate School of Environmental Studies, Tohoku University , Aramaki-Aoba, Aoba-ku, Sendai, 980-8579,  Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"10610278"},{"@type":"EISSN","@value":"10290478"}],"prism:publicationName":[{"@value":"Supramolecular Chemistry"}],"dc:publisher":[{"@value":"Informa UK Limited"}],"prism:publicationDate":"2011-01-01","prism:volume":"23","prism:number":"1-2","prism:startingPage":"160","prism:endingPage":"168"},"reviewed":"false","url":[{"@id":"https://www.tandfonline.com/doi/pdf/10.1080/10610278.2010.514915"}],"createdAt":"2011-02-23","modifiedAt":"2020-09-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360021390577666560","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Lanthanide-calixarene complexes and their applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1360286993069980928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Hetero-multinuclear Metal Complexes by Site-Selective Redox Switching and Transmetalation on a Homo-multinuclear Complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567182137075968","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The role of cadmium(II) bridges in the self-assembly with lanthanide(III) and thiacalix[4]arene (TCAS) to selectively form a luminescent ternary CdII2·TbIII2·TCAS2 complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360576118785775744","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Drastic Enhancement of Photosensitized Energy Transfer Efficiency of a Eu(III) Complex Driven by Arsenic"}]},{"@id":"https://cir.nii.ac.jp/crid/1360588379379670528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selective arrangement of three types of calcium–terbium tetranuclear cores by a thiacalixarene ligand using thermodynamic and kinetic strategies"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658121610752","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Highly Efficient Near-Infrared-Emitting Lanthanide(III) Complexes Formed by Heterogeneous Self-Assembly of Ag<sup>I</sup>, Ln<sup>III</sup>, and Thiacalix[4]arene-<i>p</i>-tetrasulfonate in Aqueous Solution (Ln<sup>III</sup> = Nd<sup>III</sup>, Yb<sup>III</sup>)"}]},{"@id":"https://cir.nii.ac.jp/crid/1390854968910564224","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of a Selective Synthesis Method and Evaluation of Luminescence Properties of A Heteronuclear Lanthanide-Thiacalixarene Complex"},{"@language":"ja","@value":"異核ランタニド—チアカリックスアレーン錯体の選択的合成法の開発と発光特性の評価"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1080/10610278.2010.514915"},{"@type":"OPENAIRE","@value":"doi_dedup___::3aaa3be597e2b1803d4d6a4b4297f1f8"},{"@type":"CROSSREF","@value":"10.1021/jacs.9b04123_references_DOI_Mx4B4ao3ravERaA8BNT2x6lSqhI"},{"@type":"CROSSREF","@value":"10.2116/bunsekikagaku.71.145_references_DOI_Mx4B4ao3ravERaA8BNT2x6lSqhI"},{"@type":"CROSSREF","@value":"10.1016/bs.hpcre.2022.08.001_references_DOI_Mx4B4ao3ravERaA8BNT2x6lSqhI"},{"@type":"CROSSREF","@value":"10.1021/acs.inorgchem.1c00577_references_DOI_Mx4B4ao3ravERaA8BNT2x6lSqhI"},{"@type":"CROSSREF","@value":"10.1039/d4ra08259a_references_DOI_Mx4B4ao3ravERaA8BNT2x6lSqhI"},{"@type":"CROSSREF","@value":"10.1021/ic2019583_references_DOI_Mx4B4ao3ravERaA8BNT2x6lSqhI"},{"@type":"CROSSREF","@value":"10.1016/j.ica.2012.11.016_references_DOI_Mx4B4ao3ravERaA8BNT2x6lSqhI"}]}