{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699995919976960.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ic202635a"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ic202635a"}},{"identifier":{"@type":"PMID","@value":"22734924"}}],"dc:title":[{"@value":"Solvent-Induced Controllable Synthesis, Single-Crystal to Single-Crystal Transformation and Encapsulation of Alq3 for Modulated Luminescence in (4,8)-Connected Metal–Organic Frameworks"}],"description":[{"notation":[{"@value":"In this work, for the first time, we have systematically demonstrated that solvent plays crucial roles in both controllable synthesis of metal-organic frameworks (MOFs) and their structural transformation process. With solvent as the only variable, five new MOFs with different structures have been constructed, in which one MOF undergoes solvent-induced single-crystal to single-crystal (SCSC) transformation that involves not only solvent exchange but also the cleavage and formation of coordination bonds. Particularly, a significant crystallographic change has been realized through an unprecedented three-step SCSC transformation process. Furthermore, we have demonstrated that the obtained MOF could be an excellent host for chromophores such as Alq3 for modulated luminescent properties."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699995919976961","@type":"Researcher","foaf:name":[{"@value":"Ya-Qian Lan"}],"jpcoar:affiliationName":[{"@value":"National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan"},{"@value":"Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R.\rChina"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699995919976960","@type":"Researcher","foaf:name":[{"@value":"Hai-Long Jiang"}],"jpcoar:affiliationName":[{"@value":"National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699995919976962","@type":"Researcher","foaf:name":[{"@value":"Shun-Li Li"}],"jpcoar:affiliationName":[{"@value":"Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R.\rChina"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699995919976963","@type":"Researcher","foaf:name":[{"@value":"Qiang Xu"}],"jpcoar:affiliationName":[{"@value":"National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00201669"},{"@type":"EISSN","@value":"1520510X"}],"prism:publicationName":[{"@value":"Inorganic Chemistry"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2012-06-26","prism:volume":"51","prism:number":"14","prism:startingPage":"7484","prism:endingPage":"7491"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ic202635a"}],"createdAt":"2012-06-27","modifiedAt":"2023-04-05","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233609957248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Solid state conversion of a double helix thallium(<scp>i</scp>) coordination polymer to a corrugated tape silver(<scp>i</scp>) polymer"}]},{"@id":"https://cir.nii.ac.jp/crid/1360849942920534784","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Heterochiral-to-Homochiral Structural Transformation in Metallosupramolecular Ionic Crystals"}]},{"@id":"https://cir.nii.ac.jp/crid/1880302168274580864","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850059: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1881146592566571520","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850054: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1881709542438426112","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850052: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1881709542447298432","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850058: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1881991017568471808","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850057: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1882835443143867264","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850056: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1883679867419644032","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850055: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1883679867576290944","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850051: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1884242817890472448","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 850053: Experimental Crystal Structure Determination"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/ic202635a"},{"@type":"OPENAIRE","@value":"doi_dedup___::66859a910aab9b0b3fb9b4c36df1b5c6"},{"@type":"CROSSREF","@value":"10.1039/c6ra09423f_references_DOI_AutzgcQAllejfUHgW9YK6m1IyNv"},{"@type":"CROSSREF","@value":"10.1021/acs.inorgchem.0c00308_references_DOI_AutzgcQAllejfUHgW9YK6m1IyNv"}]}