{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699996000108288.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/adsc.201500510"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.201500510"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.201500510"}}],"dc:title":[{"@value":"Copper‐Catalyzed Cascade Cyclization for the Synthesis of Trifluoromethyl‐Substituted Spiro‐2<i>H</i>‐azirines from 1,6‐Enynes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A method for the synthesis of trifluoromethyl CF<jats:sub>3</jats:sub>‐substituted spirocyclic compounds containing with a unique quaternary carbon center from readily available starting materials has been developed. The reaction provides a facile access to 2<jats:italic>H</jats:italic>‐azirines <jats:italic>via</jats:italic> cascade cyclization. These compounds constitute a new class of functionalized synthetic intermediates, which can be used for the synthesis of various nitrogen‐containing heterocycles and biologically active CF<jats:sub>3</jats:sub>‐containing compounds.</jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" mimetype=\"image/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic/mcontent.gif\"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380298345155179395","@type":"Researcher","foaf:name":[{"@value":"Yu‐Tao He"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996000108294","@type":"Researcher","foaf:name":[{"@value":"Qiang Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996000108160","@type":"Researcher","foaf:name":[{"@value":"Jiahui Zhao"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298345155179396","@type":"Researcher","foaf:name":[{"@value":"Xiao‐Zhen Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298345155179393","@type":"Researcher","foaf:name":[{"@value":"Yi‐Feng Qiu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298345155179398","@type":"Researcher","foaf:name":[{"@value":"Yu‐Chen Yang"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298345155179397","@type":"Researcher","foaf:name":[{"@value":"Jing‐Yuan Hu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298345155179392","@type":"Researcher","foaf:name":[{"@value":"Xue‐Yuan Liu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298345155179394","@type":"Researcher","foaf:name":[{"@value":"Yong‐Min Liang"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16154150"},{"@type":"EISSN","@value":"16154169"}],"prism:publicationName":[{"@value":"Advanced Synthesis & Catalysis"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-09-11","prism:volume":"357","prism:number":"14-15","prism:startingPage":"3069","prism:endingPage":"3075"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.201500510"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.201500510"}],"createdAt":"2015-09-11","modifiedAt":"2025-10-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/2050588892096788096","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkylation methods for synthesizing versatile building blocks"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/adsc.201500510"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190080_references_DOI_52laWYAd5IiAsLUGUF1y6N9AXu"}]}