{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699996126866816.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jp952183v"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jp952183v"}}],"dc:title":[{"@value":"Gold Particles Deposited on Electrodes in Salt Solutions under Different Potentials"}],"description":[{"notation":[{"@value":"The crystal habit of gold particles formed on an amorphous carbon film at different electrode potentials in salt solutions was studied by means of transmission electron microscopy. It was found that the results of this experiment are consistent with the results of our previous experiments using acid solutions. That is, the gold particles grown at negative electrode potentials vs SCE are mainly decahedral and icosahedral, while the particles formed at positive electrode potentials vs SCE are normal fcc octahedral particles and polycrystalline particles. As the surface energy of the hexagonal structure is lower than that of the (1×1) structure under negative electrode potentials (SCE), the shape of fine gold particles is influenced by the negative electrode potential. We also found an interesting phenomenon of agglomeration of the gold particles at electrode potentials more negative than that of hydrogen evolution."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699996126866817","@type":"Researcher","foaf:name":[{"@value":"Da-Ling Lu"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo, 7-22-1, Roppongi, Minato-ku, Tokyo 106, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996126866816","@type":"Researcher","foaf:name":[{"@value":"Ken-ichi Tanaka"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo, 7-22-1, Roppongi, Minato-ku, Tokyo 106, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00223654"},{"@type":"EISSN","@value":"15415740"}],"prism:publicationName":[{"@value":"The Journal of Physical Chemistry"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"1996-01-01","prism:volume":"100","prism:number":"5","prism:startingPage":"1833","prism:endingPage":"1837"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jp952183v"}],"createdAt":"2002-07-26","modifiedAt":"2021-09-21","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390001206459053440","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"電位制御によるAuの多重双晶粒子の生成とAu表面の再構成"},{"@language":"en","@value":"Potential Dependent Formation of Multi-twin Au Particles and Potential Induced Surface Reconstruction of Au"},{"@language":"ja-Kana","@value":"デンイ セイギョ ニ ヨル Au ノ タジュウソウショウリュウシ ノ セイセイ ト Au ヒョウメン ノ サイコウセイ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681473444480","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrocatalysis by Nanoparticles: Fabrication and Electrochemical Applications of Tailor-Designed Nanoparticles-Based Electrocatalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/2051996266988237312","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of chloroauric acid from gold electrodes in alkali halide salt solution by AC electrolysis and the sequential formation of gold nanoparticles by Turkevich method"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/jp952183v"},{"@type":"OPENAIRE","@value":"doi_dedup___::f3625d84981746e844324ba00671c86a"},{"@type":"CROSSREF","@value":"10.1246/cl.200554_references_DOI_ojd2foYF3c3kGql605xHo4tUI2"},{"@type":"CROSSREF","@value":"10.5796/electrochemistry.75.858_references_DOI_ojd2foYF3c3kGql605xHo4tUI2"},{"@type":"CROSSREF","@value":"10.1380/jsssj.26.585_references_DOI_ojd2foYF3c3kGql605xHo4tUI2"}]}