{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699996300087552.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ja105277u"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ja105277u"}},{"identifier":{"@type":"PMID","@value":"20677751"}}],"dc:title":[{"@value":"Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions"}],"description":[{"notation":[{"@value":"Reaction of lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-ide with borane.THF provides the first boryl-substituted borohydride: lithium [1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-yl]trihydroborate. The compound is fully characterized by (11)B, (1)H, and (7)Li NMR spectra and other means, and these data are compared to neutral and anionic benchmark compounds. The compound crystallizes as a dimer complexed to four THF molecules. The dimer lacks the bridging B-H bonds seen in neutral boranes and is instead held together by ionic Li---HB interactions. A preliminary scan of reactions with several iodides shows that the compound participates in an ionic reduction (with a primary-alkyl iodide), an organometallic reduction (Pd-catalyzed with an aryl iodide), and a radical reduction (AIBN-initiated with a sugar-derived iodide). Accordingly the new borylborohydride class may share properties of both traditional borohydrides and isoelectronic N-heterocyclic carbene boranes."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699996300087554","@type":"Researcher","foaf:name":[{"@value":"Kyoko Nozaki"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, and UPMC Univ Paris 06, Institut Parisien De Chimie Moléculaire (UMR CNRS 7201), C 229, 4 place Jussieu, 75005 Paris, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996300087558","@type":"Researcher","foaf:name":[{"@value":"Yoshitaka Aramaki"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, and UPMC Univ Paris 06, Institut Parisien De Chimie Moléculaire (UMR CNRS 7201), C 229, 4 place Jussieu, 75005 Paris, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996300087552","@type":"Researcher","foaf:name":[{"@value":"Makoto Yamashita"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, and UPMC Univ Paris 06, Institut Parisien De Chimie Moléculaire (UMR CNRS 7201), C 229, 4 place Jussieu, 75005 Paris, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996300087553","@type":"Researcher","foaf:name":[{"@value":"Shau-Hua Ueng"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, and UPMC Univ Paris 06, Institut Parisien De Chimie Moléculaire (UMR CNRS 7201), C 229, 4 place Jussieu, 75005 Paris, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996300087557","@type":"Researcher","foaf:name":[{"@value":"Max Malacria"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, and UPMC Univ Paris 06, Institut Parisien De Chimie Moléculaire (UMR CNRS 7201), C 229, 4 place Jussieu, 75005 Paris, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996300087556","@type":"Researcher","foaf:name":[{"@value":"Emmanuel Lacôte"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, and UPMC Univ Paris 06, Institut Parisien De Chimie Moléculaire (UMR CNRS 7201), C 229, 4 place Jussieu, 75005 Paris, France"}]},{"@id":"https://cir.nii.ac.jp/crid/1381699996300087555","@type":"Researcher","foaf:name":[{"@value":"Dennis P. Curran"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-8656, Japan, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA, and UPMC Univ Paris 06, Institut Parisien De Chimie Moléculaire (UMR CNRS 7201), C 229, 4 place Jussieu, 75005 Paris, France"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2010-08-02","prism:volume":"132","prism:number":"33","prism:startingPage":"11449","prism:endingPage":"11451"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ja105277u"}],"createdAt":"2010-08-02","modifiedAt":"2023-03-22","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Ions","dc:title":"Ions"},{"@id":"https://cir.nii.ac.jp/all?q=Models,%20Molecular","dc:title":"Models, Molecular"},{"@id":"https://cir.nii.ac.jp/all?q=Free%20Radicals","dc:title":"Free Radicals"},{"@id":"https://cir.nii.ac.jp/all?q=Molecular%20Structure","dc:title":"Molecular Structure"},{"@id":"https://cir.nii.ac.jp/all?q=Stereoisomerism","dc:title":"Stereoisomerism"},{"@id":"https://cir.nii.ac.jp/all?q=540","dc:title":"540"},{"@id":"https://cir.nii.ac.jp/all?q=Crystallography,%20X-Ray","dc:title":"Crystallography, X-Ray"},{"@id":"https://cir.nii.ac.jp/all?q=Borates","dc:title":"Borates"},{"@id":"https://cir.nii.ac.jp/all?q=Organometallic%20Compounds","dc:title":"Organometallic Compounds"},{"@id":"https://cir.nii.ac.jp/all?q=Oxidation-Reduction","dc:title":"Oxidation-Reduction"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050845763735955456","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene"},{"@value":"Isolation and Characterization of Radical Anions Derived from a Boryl‐Substituted Diphosphene"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002214423251968","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Borylcyanocuprate in a One‐Pot Carboboration by a Sequential Reaction with an Electron‐Deficient Alkyne and an Organic 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