{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361699996401077376.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.1696720"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/43/12/4479/18841729/4479_1_online.pdf"}}],"dc:title":[{"@value":"Power Series Representation of Generalized Oscillator Strengths"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Expansion of generalized oscillator strengths in powers of the momentum change K (of the colliding electron) generally leads to series with finite radii of convergence. From a study of singularities of the function for complex values of K it is possible to transform the series into one which converges for all physically attainable values of K. The transformation depends on the ionization potential and the excitation energy, both of which can be determined experimentally. The transformed series should be useful in fitting experimental data and in the extrapolation of oscillator strengths. It is especially useful, however, when applied to transitions for which a few terms of the series in inverse powers of K can be obtained. As an example the 11S→21S transition in helium is treated. The mere determination of the degree of the first nonvanishing term in the inverse power series is enough to severely restrict the form of series and, in fact, to sum the first six terms. These terms, which involve only one adjustable constant, fit the experimental data to within 3.5% and the deviation is mainly due to experimental error.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381699996401077376","@type":"Researcher","foaf:name":[{"@value":"Edwin N. Lassettre"}],"jpcoar:affiliationName":[{"@value":"Mellon Institute, 4400 Fifth Avenue, Pittsburgh, Pennsylvania"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"1965-12-15","prism:volume":"43","prism:number":"12","prism:startingPage":"4479","prism:endingPage":"4486"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/43/12/4479/18841729/4479_1_online.pdf"}],"createdAt":"2005-01-09","modifiedAt":"2024-02-09","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233894894336","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A study of electron scattering from benzene: Excitation of the 1B1<i>u</i>, 3E2<i>g</i>, and 1E1<i>u</i> electronic states"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233911214208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Intermediate-energy differential and integral cross sections for vibrational excitation in α-tetrahydrofurfuryl alcohol"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846642032373248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"An experimental and theoretical investigation into the excited electronic states of phenol"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644035457280","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Looking at Molecular Orbitals in Three-Dimensional Form: From Dream to Reality"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658824090368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electron excitation of the Schumann–Runge continuum, longest band, and second band electronic states in O2"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658839423744","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electron impact excitation of the low-lying 3<i>s</i>[3/2]1 and 3<i>s</i>′[1/2]1 levels in neon for incident energies between 20 and 300 eV"}]},{"@id":"https://cir.nii.ac.jp/crid/1390846609792396160","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Molecular Science Using Electron Collisions"},{"@language":"ja","@value":"電子衝突で挑む分子科学"},{"@language":"ja-Kana","@value":"デンシ ショウトツ デ イドム ブンシ カガク"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1063/1.1696720"},{"@type":"CROSSREF","@value":"10.1063/1.3575497_references_DOI_Qa9bEI0rwkx2lhjw7YE929CXHz4"},{"@type":"CROSSREF","@value":"10.1063/1.4879779_references_DOI_Qa9bEI0rwkx2lhjw7YE929CXHz4"},{"@type":"CROSSREF","@value":"10.1246/bcsj.82.751_references_DOI_Qa9bEI0rwkx2lhjw7YE929CXHz4"},{"@type":"CROSSREF","@value":"10.1063/1.4893116_references_DOI_Qa9bEI0rwkx2lhjw7YE929CXHz4"},{"@type":"CROSSREF","@value":"10.1063/1.3533442_references_DOI_Qa9bEI0rwkx2lhjw7YE929CXHz4"},{"@type":"CROSSREF","@value":"10.1063/1.4829056_references_DOI_Qa9bEI0rwkx2lhjw7YE929CXHz4"},{"@type":"CROSSREF","@value":"10.1380/vss.63.13_references_DOI_Qa9bEI0rwkx2lhjw7YE929CXHz4"}]}