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Instead of a displacement of the dinitrogen moiety, which is the common mode of reactivity, a complex containing both a bridging hydride and a bridging hydrazido unit with a nitrogen-hydrogen bond was observed. This reaction was extended to primary silanes to produce a species that contained a nitrogen-silicon bond. In addition, an intermediate in the dihydrogen addition has been structurally characterized as having a bridging dihydrogen unit.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381981469295239299","@type":"Researcher","foaf:name":[{"@value":"Michael D. Fryzuk"}],"jpcoar:affiliationName":[{"@value":"M. D. Fryzuk, J. B. Love, S. J. Rettig, Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada."}]},{"@id":"https://cir.nii.ac.jp/crid/1381981469295239296","@type":"Researcher","foaf:name":[{"@value":"Jason B. Love"}],"jpcoar:affiliationName":[{"@value":"M. D. Fryzuk, J. B. Love, S. J. Rettig, Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada."}]},{"@id":"https://cir.nii.ac.jp/crid/1381981469295239298","@type":"Researcher","foaf:name":[{"@value":"Steven J. Rettig"}],"jpcoar:affiliationName":[{"@value":"M. D. Fryzuk, J. B. Love, S. J. Rettig, Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada."}]},{"@id":"https://cir.nii.ac.jp/crid/1381981469295239297","@type":"Researcher","foaf:name":[{"@value":"Victor G. Young"}],"jpcoar:affiliationName":[{"@value":"V. G. 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