{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361981469721338496.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ja305596v"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ja305596v"}}],"dc:title":[{"@value":"Iridium-Catalyzed Borylation of Secondary C–H Bonds in Cyclic Ethers"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381981469721338496","@type":"Researcher","foaf:name":[{"@value":"Carl W. Liskey"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, University of Illinois, 600 South Mathews Avenue, Urbana, Illinois 61801, United States"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981469721338497","@type":"Researcher","foaf:name":[{"@value":"John F. Hartwig"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, University of California, Berkeley, California 94720, United States"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2012-07-20","prism:volume":"134","prism:number":"30","prism:startingPage":"12422","prism:endingPage":"12425"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ja305596v"}],"createdAt":"2012-07-18","modifiedAt":"2024-04-27","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050306506449956864","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"An Electron-Deficient Cp-E Iridium(III) Catalyst: Synthesis, Characterization, and Application to Ether-Directed C-H Amidation"},{"@value":"An Electron‐Deficient Cp<sup>E</sup> Iridium(III) Catalyst: Synthesis, Characterization, and Application to Ether‐Directed C−H Amidation"}]},{"@id":"https://cir.nii.ac.jp/crid/1050306506451857152","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Synthesis of 2-alkyl-2-boryl-substituted-tetrahydrofurans via copper(i)-catalysed borylative cyclization of aliphatic ketones"},{"@value":"Synthesis of 2-alkyl-2-boryl-substituted-tetrahydrofurans <i>via</i> copper(<scp>i</scp>)-catalysed borylative cyclization of aliphatic ketones"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002214425228544","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ligand‐Promoted Borylation of C(sp<sup>3</sup>)H Bonds with Palladium(II) Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017282231328768","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"An Iridium/Aluminum Cooperative Strategy for the β‐C(sp<sup>3</sup>)‐H Borylation of Saturated Cyclic Amines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360025430197403008","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selective Borylation of C(sp<sup>3</sup>)−H Bond of Methyl Ethers Catalyzed by Iron Complexes Bearing Anionic Benzene‐Based PCP‐Pincer Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283689443118208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Stereoselective CH Borylations of Cyclopropanes and Cyclobutanes with Silica‐Supported Monophosphane–Ir Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691636696192","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Total Synthesis of Verruculogen and Fumitremorgin A Enabled by Ligand-Controlled C–H Borylation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285704859175936","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Silica‐Supported Tripod Triarylphosphane: Application to Transition Metal‐Catalyzed C(<i>sp</i><sup>3</sup>)H Borylations"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285707501680512","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cationic iridium-catalyzed enantioselective activation of secondary sp3 C–H bond adjacent to nitrogen atom"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708560716928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp<sup>3</sup>)–H bonds adjacent to a nitrogen atom"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298339717757568","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Iridium‐Catalyzed C(sp<sup>3</sup>)−H Borylation Using Silyl‐Bipyridine Pincer Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1360306905635718144","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ir-Catalyzed, Nitrogen-Directed C(sp<sup>3</sup>)–H and C(sp<sup>2</sup>)–H Borylation with a Spiro-Fluorene-Indenoindenyl Ligand"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565164378179584","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Stereodivergent Synthesis of Arylcyclopropylamines by Sequential CH Borylation and Suzuki–Miyaura Coupling"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166611931136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp<sup>3</sup>)–H Borylation of Methylchlorosilanes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166611999488","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Primary and Secondary Alkylboronates through Site-Selective C(sp<sup>3</sup>)–H Activation with Silica-Supported Monophosphine–Ir Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166612220800","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Arylboration of Alkenes by Cooperative Palladium/Copper Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166833404416","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Iridium-catalyzed triple C(sp3)–H borylations: construction of triborylated sp3-carbon centers"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166849201536","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Formal nucleophilic borylation and borylative cyclization of organic halides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169059052032","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Rhodium-catalyzed Borylation of Aryl and Alkenyl Pivalates through the Cleavage of Carbon–Oxygen Bonds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183084301312","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp<sup>3</sup>)–H Borylation at the Methyl Group on Silicon"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183167414912","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Rhodium-Catalyzed Borylation of Aryl 2-Pyridyl Ethers through Cleavage of the Carbon–Oxygen Bond: Borylative Removal of the Directing Group"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092608198528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"1,2-Arylboration of aliphatic alkenes by cooperative palladium/copper catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092664391680","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"σ-Bond Hydroboration of Cyclopropanes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360572092873841920","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Asymmetric Synthesis of α-Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp<sup>3</sup>)–H Borylation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641813840768","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Iridium-catalysed borylation of sterically hindered C(sp<sup>3</sup>)–H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658071269504","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp<sup>3</sup>)–H Borylation and Conversion to Functionalized Siloxanes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694367953434112","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"sp<sup>3</sup> C–H Borylation Catalyzed by Iridium(III) Triboryl Complex: Comprehensive Theoretical Study of Reactivity, Regioselectivity, and Prediction of Excellent Ligand"}]},{"@id":"https://cir.nii.ac.jp/crid/1361975842847545984","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Boryl-Directed, Ir-Catalyzed C(sp<sup>3</sup>)–H Borylation of Alkylboronic Acids Leading to Site-Selective Synthesis of Polyborylalkanes"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204141347840","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Alkynoxy-Directed C–H Functionalizations: Palladium(0)-Catalyzed Annulations of Alkynyl Aryl Ethers with Alkynes"},{"@value":"Selected Paper : Alkynoxy-Directed C-H Functionalizations : Palladium(0)-Catalyzed Annulations of Alkynyl Aryl Ethers with Alkynes"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680316306176","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"C(sp<sup>3</sup>)-H結合のシリル化およびトリホウ素化，続く二酸化炭素によるカルボキシル化の開発"},{"@language":"en","@value":"Development of Catalytic C(sp<sup>3</sup>)-H Silylation and Triborylation Followed by Carboxylation with CO<sub>2</sub>"},{"@value":"C(sp³)-H結合のシリル化およびトリホウ素化,続く二酸化炭素によるカルボキシル化の開発"},{"@language":"ja-Kana","@value":"C(sp ³)-H ケツゴウ ノ シリルカ オヨビ トリホウソカ,ツズク ニサンカ タンソ ニ ヨル カルボキシルカ ノ カイハツ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390294330154220672","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Catalytic Reactions that Enable Efficient Conversions of sp<sup>3</sup> Carbon-Hydrogen and Carbon-Boron Bonds"},{"@language":"ja","@value":"sp<sup>3</sup>炭素-水素および炭素-ホウ素結合の触媒的高効率変換反応の開発"}]},{"@id":"https://cir.nii.ac.jp/crid/2051433317024739968","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fourfold C-H borylation of anthracene : 1,3,5,7-tetraborylanthracene and its application to 1,3,5,7-tetraarylanthracenes"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714792003846528","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Catalyst-enabled site-selectivity in the iridium-catalyzed C-H borylation of arenes"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/ja305596v"},{"@type":"CROSSREF","@value":"10.1002/anie.201509996_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1039/c9ob00962k_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/ja307956w_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1002/anie.202300704_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1002/ceur.202400100_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1002/chem.201404362_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1002/adsc.201301147_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1039/c4cc09508a_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/ja3126239_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/jacs.5b07154_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/acs.joc.6b02917_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/acs.organomet.6b00316_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.5059/yukigoseikyokaishi.73.810_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1002/anie.202202327_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1002/anie.202301259_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/acscatal.4c07249_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1002/anie.201409186_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1039/c3cc42675k_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1039/c6ob02369j_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.9b02112_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/jacs.9b01767_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1016/j.tetlet.2021.153059_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/jacs.0c05213_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/jacs.9b12013_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1039/c4cc01262c_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/ja511622e_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1016/j.tet.2012.08.071_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1246/cl.190372_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1246/cl.170037_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.5059/yukigoseikyokaishi.80.1113_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20150180_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1021/ja5029556_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"},{"@type":"CROSSREF","@value":"10.1246/cl.141084_references_DOI_a6r49OGNz4KKFb3Ghuuazw4x2Jj"}]}