{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361981470127105152.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.1409582"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jap/article-pdf/90/10/5048/19013425/5048_1_online.pdf"}}],"dc:title":[{"@value":"Nearly 100% internal phosphorescence efficiency in an organic light-emitting device"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>We demonstrate very high efficiency electrophosphorescence in organic light-emitting devices employing a phosphorescent molecule doped into a wide energy gap host. Using bis(2-phenylpyridine)iridium(III) acetylacetonate [(ppy)2Ir(acac)] doped into 3-phenyl-4(1′-naphthyl)-5-phenyl-1,2,4-triazole, a maximum external quantum efficiency of (19.0±1.0)% and luminous power efficiency of (60±5) lm/W are achieved. The calculated internal quantum efficiency of (87±7)% is supported by the observed absence of thermally activated nonradiative loss in the photoluminescent efficiency of (ppy)2Ir(acac). Thus, very high external quantum efficiencies are due to the nearly 100% internal phosphorescence efficiency of (ppy)2Ir(acac) coupled with balanced hole and electron injection, and triplet exciton confinement within the light-emitting layer.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381981470127105154","@type":"Researcher","foaf:name":[{"@value":"Chihaya Adachi"}],"jpcoar:affiliationName":[{"@value":"Center for Photonics and Optoelectronic Materials (POEM), Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981470127105155","@type":"Researcher","foaf:name":[{"@value":"Marc A. Baldo"}],"jpcoar:affiliationName":[{"@value":"Center for Photonics and Optoelectronic Materials (POEM), Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981470127105152","@type":"Researcher","foaf:name":[{"@value":"Mark E. Thompson"}],"jpcoar:affiliationName":[{"@value":"Center for Photonics and Optoelectronic Materials (POEM), Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981470127105153","@type":"Researcher","foaf:name":[{"@value":"Stephen R. Forrest"}],"jpcoar:affiliationName":[{"@value":"Center for Photonics and Optoelectronic Materials (POEM), Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00218979"},{"@type":"EISSN","@value":"10897550"}],"prism:publicationName":[{"@value":"Journal of Applied Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"2001-11-15","prism:volume":"90","prism:number":"10","prism:startingPage":"5048","prism:endingPage":"5051"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jap/article-pdf/90/10/5048/19013425/5048_1_online.pdf"}],"createdAt":"2002-07-26","modifiedAt":"2024-02-10","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050001202553797248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Luminescent Ir(III) complexes containing 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