{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361981470192244352.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jp0204861"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jp0204861"}}],"dc:title":[{"@value":"Extended X-ray Absorption Fine Structure Studies on the Structure of the Poly(vinylpyrrolidone)-Stabilized Cu/Pd Nanoclusters Colloidally Dispersed in Solution"}],"description":[{"notation":[{"@value":"Polymer-protected Cu/Pd bimetallic nanoclusters colloidally dispersed in a glycol solution were investigated by means of extended X-ray absorption fine structure (EXAFS). Cu/Pd alloy structures were observed in a wide range of Cu/Pd composition. Shorter Cu−Pd bond distances and more coordination numbers of Cu around Pd and Pd around Cu were found for the nanoclusters with Cu/Pd = 4:1, 3:2, and 1:1 than those expected in random alloy structures, indicating stronger interaction between Cu and Pd atoms. We proposed a “heterobond-philic” model for a new type of bimetallic nanoclusters. The preferential formation of the Cu−Pd bond may be the origin for the unique catalytic properties for hydration and hydrogenation reactions."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381981470192244354","@type":"Researcher","foaf:name":[{"@value":"Cui-Rong Bian"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981470192244352","@type":"Researcher","foaf:name":[{"@value":"Shushi Suzuki"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981470192244356","@type":"Researcher","foaf:name":[{"@value":"Kiyotaka Asakura"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981470192244353","@type":"Researcher","foaf:name":[{"@value":"Lu Ping"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981470192244355","@type":"Researcher","foaf:name":[{"@value":"Naoki Toshima"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"15206106"},{"@type":"EISSN","@value":"15205207"}],"prism:publicationName":[{"@value":"The Journal of Physical Chemistry B"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2002-08-01","prism:volume":"106","prism:number":"34","prism:startingPage":"8587","prism:endingPage":"8598"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jp0204861"}],"createdAt":"2002-09-17","modifiedAt":"2023-03-16","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219110531328","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cu–Pd Bimetallic Cluster/AC as a Novel Catalyst for the Reduction of Nitrate to Nitrite"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691586590208","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"<i>In Situ</i>X-ray Absorption Fine Structure Analysis of PtCo, PtCu, and PtNi Alloy Electrocatalysts: The Correlation of Enhanced Oxygen Reduction Reaction Activity and Structure"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183078336256","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Microwave-Assisted Polyol Synthesis of Pt/Pd and Pt/Rh Bimetallic Nanoparticles in Polymer Solutions Prepared by Batch and Continuous-Flow Processing"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183511864192","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Production of an ordered (B2) CuPd nanoalloy by low-temperature annealing under hydrogen atmosphere"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205190251648","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"CO Tolerant Anode Catalyst for Residential Fuel Cell System"},{"@language":"ja","@value":"家庭用燃料電池システムに用いるCO耐性燃料極触媒"},{"@language":"ja-Kana","@value":"カテイヨウ ネンリョウ デンチ システム ニ モチイル CO タイセイ ネンリョウキョク ショクバイ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390003825203583744","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Thorough Search Analysis of Extended X-ray Absorption Fine Structure Data for Complex Molecules and Nanomaterials Applications"}]},{"@id":"https://cir.nii.ac.jp/crid/2050025942159561856","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Constrained thorough search analysis of multi-edge EXAFS spectra for characterization of bimetallic nanoparticles"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/jp0204861"},{"@type":"OPENAIRE","@value":"doi_dedup___::bc08c793b21a3168f8c63ac656012cbd"},{"@type":"CROSSREF","@value":"10.1246/cl.2004.908_references_DOI_XEjX9x34U7xvZgjWcxfqdtOSBPJ"},{"@type":"CROSSREF","@value":"10.1246/cl.220090_references_DOI_XEjX9x34U7xvZgjWcxfqdtOSBPJ"},{"@type":"CROSSREF","@value":"10.1039/c0dt01632b_references_DOI_XEjX9x34U7xvZgjWcxfqdtOSBPJ"},{"@type":"CROSSREF","@value":"10.1380/ejssnt.2020.249_references_DOI_XEjX9x34U7xvZgjWcxfqdtOSBPJ"},{"@type":"CROSSREF","@value":"10.1627/jpi.58.64_references_DOI_XEjX9x34U7xvZgjWcxfqdtOSBPJ"},{"@type":"CROSSREF","@value":"10.1021/acs.jpcc.6b01736_references_DOI_XEjX9x34U7xvZgjWcxfqdtOSBPJ"},{"@type":"CROSSREF","@value":"10.1021/acs.iecr.7b03154_references_DOI_XEjX9x34U7xvZgjWcxfqdtOSBPJ"}]}