{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361981471048083584.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1071/ch07231"}},{"identifier":{"@type":"URI","@value":"https://connectsci.au/ch/article-pdf/60/11/821/1029443/ch07231.pdf"}}],"dc:title":[{"@value":"Selective Monoesterification of Malonic Acid Catalyzed by Boric Acid"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Boric acid catalyzes the monoesterification of malonic acid, likely through a chelation mechanism that is not available to the monoester product. Under more forcing conditions, diesters form to some extent, but conditions can be optimized to favour the monoester product (56–80%). With the easily handled solid acid catalyst, these reactions can be run with excess alcohol as solvent or with stoichiometric amounts of alcohol in acetonitrile with moderate heating.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381981471048083585","@type":"Researcher","foaf:name":[{"@value":"Stephan M. Levonis"}],"jpcoar:affiliationName":[{"@value":"AInstitute for Glycomics, Gold Coast Campus, Griffith University, Qld 4222, Australia."}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471048083586","@type":"Researcher","foaf:name":[{"@value":"Laurent F. Bornaghi"}],"jpcoar:affiliationName":[{"@value":"AInstitute for Glycomics, Gold Coast Campus, Griffith University, Qld 4222, Australia."}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471048083584","@type":"Researcher","foaf:name":[{"@value":"Todd A. Houston"}],"jpcoar:affiliationName":[{"@value":"AInstitute for Glycomics, Gold Coast Campus, Griffith University, Qld 4222, Australia."},{"@value":"BCorresponding author. Email: t.houston@griffith.edu.au"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00049425"},{"@type":"EISSN","@value":"14450038"}],"prism:publicationName":[{"@value":"Australian Journal of Chemistry"}],"dc:publisher":[{"@value":"CSIRO Publishing"}],"prism:publicationDate":"2007-11-01","prism:volume":"60","prism:number":"11","prism:startingPage":"821","prism:endingPage":"823"},"reviewed":"false","dc:rights":["https://doi.org/10.1071/journalslicense"],"url":[{"@id":"https://connectsci.au/ch/article-pdf/60/11/821/1029443/ch07231.pdf"}],"createdAt":"2007-11-01","modifiedAt":"2025-12-15","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233142447104","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Boronic Acid Accelerated Three-Component Reaction for the Synthesis of α-Sulfanyl-Substituted Indole-3-acetic Acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641612268032","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Primary Alkylboronic Acids as Highly Active Catalysts for the Dehydrative Amide Condensation of α-Hydroxycarboxylic Acids"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204358808704","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"1.4 石油化学(1. 石油,II エネルギー資源の利用技術の進展と研究動向,平成19年における重要なエネルギー関係事項)"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1071/ch07231"},{"@type":"CROSSREF","@value":"10.3775/jie.87.593_references_DOI_1pUqMsuWyh6rcxLsrhReiJRlhrS"},{"@type":"CROSSREF","@value":"10.1021/ol401537f_references_DOI_1pUqMsuWyh6rcxLsrhReiJRlhrS"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.7b02727_references_DOI_1pUqMsuWyh6rcxLsrhReiJRlhrS"}]}