{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361981471115664768.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ange.201609035"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201609035"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201609035"}}],"dc:title":[{"@value":"Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A general strategy for the cleavage and amination of C−C bonds of cycloalkanols has been achieved through visible‐light‐induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C−C bond cleavage and functionalization of unstrained secondary cycloalkanols.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380861291576672384","@type":"Researcher","foaf:name":[{"@value":"Jing‐Jing Guo"}],"jpcoar:affiliationName":[{"@value":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471115664896","@type":"Researcher","foaf:name":[{"@value":"Anhua Hu"}],"jpcoar:affiliationName":[{"@value":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471115664769","@type":"Researcher","foaf:name":[{"@value":"Yilin Chen"}],"jpcoar:affiliationName":[{"@value":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471115664768","@type":"Researcher","foaf:name":[{"@value":"Jianfeng Sun"}],"jpcoar:affiliationName":[{"@value":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471115664770","@type":"Researcher","foaf:name":[{"@value":"Haoming Tang"}],"jpcoar:affiliationName":[{"@value":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471115664897","@type":"Researcher","foaf:name":[{"@value":"Zhiwei Zuo"}],"jpcoar:affiliationName":[{"@value":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00448249"},{"@type":"EISSN","@value":"15213757"}],"prism:publicationName":[{"@value":"Angewandte Chemie"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2016-11-11","prism:volume":"128","prism:number":"49","prism:startingPage":"15545","prism:endingPage":"15548"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201609035"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201609035"}],"createdAt":"2016-11-16","modifiedAt":"2023-10-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360565164379722368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Photocatalyzed <i>ortho</i>‐Alkylation of Pyridine <i>N</i>‐Oxides through Alkene Cleavage"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ange.201609035"},{"@type":"CROSSREF","@value":"10.1002/anie.201801305_references_DOI_aCrE2HKjjwCMXudIqz9KA6tkfrs"}]}