{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361981471273239040.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/adsc.201400320"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.201400320"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.201400320"}}],"dc:title":[{"@value":"Copper‐Catalyzed Regioselective Oxytrifluoromethylation of Allenes Using a CF<sub>3</sub>‐Transfer Reagent"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A mild and efficient copper‐catalyzed oxytrifluoromethylation of allenes is demonstrated. The reaction tolerates a range of substrates to give a series of trifluoromethylated derivatives in moderate to good yields. Two possible pathways were proposed based on the reaction results and control experiments.</jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" mimetype=\"image/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic/mcontent.gif\"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381981471273239040","@type":"Researcher","foaf:name":[{"@value":"Yanan Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471273239041","@type":"Researcher","foaf:name":[{"@value":"Min Jiang"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861292509177088","@type":"Researcher","foaf:name":[{"@value":"Jin‐Tao Liu"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16154150"},{"@type":"EISSN","@value":"16154169"}],"prism:publicationName":[{"@value":"Advanced Synthesis & Catalysis"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2014-09-10","prism:volume":"356","prism:number":"14-15","prism:startingPage":"2907","prism:endingPage":"2912"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadsc.201400320"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.201400320"}],"createdAt":"2014-09-10","modifiedAt":"2025-10-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233613788672","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Photoredox-catalyzed oxytrifluoromethylation of allenes: stereoselective synthesis of 2-trifluoromethylated allyl acetates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360861705587639552","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Evolution and Future of Hetero‐ and Hydro‐Trifluoromethylations of Unsaturated C−C Bonds"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892096788096","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkylation methods for synthesizing versatile building blocks"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/adsc.201400320"},{"@type":"CROSSREF","@value":"10.1039/c7cc01759f_references_DOI_SWyxO2LLfydNVOhUpgnce1tWXvc"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190080_references_DOI_SWyxO2LLfydNVOhUpgnce1tWXvc"},{"@type":"CROSSREF","@value":"10.1002/adsc.202201268_references_DOI_SWyxO2LLfydNVOhUpgnce1tWXvc"}]}