{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361981471339418752.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.tetlet.2008.05.105"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0040403908010198?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0040403908010198?httpAccept=text/plain"}}],"dc:title":[{"@value":"Synthetic studies on the taxane skeleton: effective construction of eight-membered carbocyclic ring by palladium-catalyzed intramolecular α-alkenylation of a methyl ketone"}],"description":[{"notation":[{"@value":"A new method for the construction of the eight-membered carbocyclic ring in the taxane skeleton is described. The palladium-catalyzed intramolecular α-alkenylation of a methyl ketone effectively constructed the eight-membered carbocyclic ring in the taxol model compound. To the best of our knowledge, this reaction is the first example of forming an eight-membered carbocyclic ring by the palladium-catalyzed intramolecular α-alkenylation of a ketone."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381981471339418753","@type":"Researcher","foaf:name":[{"@value":"Masayuki Utsugi"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471339418752","@type":"Researcher","foaf:name":[{"@value":"Yasuaki Kamada"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471339418754","@type":"Researcher","foaf:name":[{"@value":"Masahisa Nakada"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00404039"}],"prism:publicationName":[{"@value":"Tetrahedron Letters"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2008-08","prism:volume":"49","prism:number":"32","prism:startingPage":"4754","prism:endingPage":"4757"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S0040403908010198?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S0040403908010198?httpAccept=text/plain"}],"createdAt":"2008-05-29","modifiedAt":"2018-12-28","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360021391882615552","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Pd-Catalyzed Stereoselective Construction of Benzo-Fused Decalines with a Quaternary Carbon"}]},{"@id":"https://cir.nii.ac.jp/crid/1360568468044032512","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Total Synthesis of Cotylenin A"}]},{"@id":"https://cir.nii.ac.jp/crid/1360576118674868096","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of the eight-membered carbocycle of brachialactone by intramolecular Mizoroki-Heck reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848657457354752","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of medium-sized carbocyclic ketones via the intramolecular B-alkyl Liebeskind–Srogl coupling reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848657457538432","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A short and enantioselective preparation of taxol A-ring fragment"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205339659136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Formal Total Synthesis of (−)-Taxol"},{"@value":"Formal Total Synthesis of (-)-Taxol"}]},{"@id":"https://cir.nii.ac.jp/crid/2050025942155224064","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Research on the efficient enantioselective total synthesis of useful bioactive polycyclic compounds"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/j.tetlet.2008.05.105"},{"@type":"OPENAIRE","@value":"doi_dedup___::5fbf0a7b9a2fac475a52f741f18d8c27"},{"@type":"CROSSREF","@value":"10.5059/yukigoseikyokaishi.75.1102_references_DOI_3rb2EC1kFVmzgxRTV3ycyVEfipT"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.3c02233_references_DOI_3rb2EC1kFVmzgxRTV3ycyVEfipT"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20210329_references_DOI_3rb2EC1kFVmzgxRTV3ycyVEfipT"},{"@type":"CROSSREF","@value":"10.1016/j.tetlet.2021.153608_references_DOI_3rb2EC1kFVmzgxRTV3ycyVEfipT"},{"@type":"CROSSREF","@value":"10.1021/jacs.0c01774_references_DOI_3rb2EC1kFVmzgxRTV3ycyVEfipT"},{"@type":"CROSSREF","@value":"10.1016/j.tetlet.2013.01.115_references_DOI_3rb2EC1kFVmzgxRTV3ycyVEfipT"},{"@type":"CROSSREF","@value":"10.1016/j.tetlet.2011.10.148_references_DOI_3rb2EC1kFVmzgxRTV3ycyVEfipT"}]}