{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361981471359924864.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201309778"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201309778"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201309778"}}],"dc:title":[{"@value":"Crystal Engineering of an nbo Topology Metal–Organic Framework for Chemical Fixation of CO<sub>2</sub> under Ambient Conditions"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Crystal engineering of the <jats:bold>nbo</jats:bold> metal–organic framework (MOF) platform MOF‐505 with a custom‐designed azamacrocycle ligand (1,4,7,10‐tetrazazcyclododecane‐<jats:italic>N</jats:italic>,<jats:italic>N</jats:italic>′,<jats:italic>N</jats:italic>′′,<jats:italic>N</jats:italic>′′′‐tetra‐<jats:italic>p</jats:italic>‐methylbenzoic acid) leads to a high density of well‐oriented Lewis active sites within the cuboctahedral cage in MMCF‐2, [Cu<jats:sub>2</jats:sub>(Cu‐tactmb)(H<jats:sub>2</jats:sub>O)<jats:sub>3</jats:sub>(NO<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub>]. This MOF demonstrates high catalytic activity for the chemical fixation of CO<jats:sub>2</jats:sub> into cyclic carbonates at room temperature under 1 atm pressure.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380579818352104192","@type":"Researcher","foaf:name":[{"@value":"Wen‐Yang Gao"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471359924867","@type":"Researcher","foaf:name":[{"@value":"Yao Chen"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471359924869","@type":"Researcher","foaf:name":[{"@value":"Youhong Niu"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471359924866","@type":"Researcher","foaf:name":[{"@value":"Kia Williams"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471359924864","@type":"Researcher","foaf:name":[{"@value":"Lindsay Cash"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471359924865","@type":"Researcher","foaf:name":[{"@value":"Pastor J. Perez"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471359924872","@type":"Researcher","foaf:name":[{"@value":"Lukasz Wojtas"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471359924871","@type":"Researcher","foaf:name":[{"@value":"Jianfeng Cai"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579818352104193","@type":"Researcher","foaf:name":[{"@value":"Yu‐Sheng Chen"}]},{"@id":"https://cir.nii.ac.jp/crid/1381981471359924736","@type":"Researcher","foaf:name":[{"@value":"Shengqian Ma"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2014-02-04","prism:volume":"53","prism:number":"10","prism:startingPage":"2615","prism:endingPage":"2619"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201309778"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201309778"}],"createdAt":"2014-02-05","modifiedAt":"2023-10-17","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050001335829997440","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand"}]},{"@id":"https://cir.nii.ac.jp/crid/1050282813764839424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Carbon dioxide capture and efficient fixation in a dynamic porous coordination polymer"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285705058810880","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Design of Zeolitic Imidazolate Framework Derived Nitrogen‐Doped Nanoporous Carbons Containing Metal Species for Carbon Dioxide Fixation Reactions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360290617537894528","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Mole-Ratio-Dependent Reversible Transformation between 2:2 and Cyclic 3:6 Silver(I) Complexes with an Argentivorous Molecule"}]},{"@id":"https://cir.nii.ac.jp/crid/1360588380132702336","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Linear regression model for metal–organic frameworks with CO2 adsorption based on topological data analysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360853567491311360","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Influence of the Molar Ratio and Solvent on the Coordination Modes of 1,7-Dibenzyl-4,10-bis(pyridin-4-ylmethyl)cyclen"}]},{"@id":"https://cir.nii.ac.jp/crid/1523388080592863360","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Selected Paper : Combined Experimental and Computational Study on Catalytic Cyclocoupling of Epoxides and CO₂ Using Porphyrin-Based Cu(Ⅱ) Metal-Organic Frameworks with 2D Coordination Networks"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892102334592","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Metal-organic cages (MOCs) : from discrete to cage-based extended architectures"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201309778"},{"@type":"CROSSREF","@value":"10.1002/cssc.201500780_references_DOI_NyqNWnhX2xS0Svv2kfmH7n4yF2q"},{"@type":"CROSSREF","@value":"10.1038/ncomms6851_references_DOI_NyqNWnhX2xS0Svv2kfmH7n4yF2q"},{"@type":"CROSSREF","@value":"10.1246/cl.190731_references_DOI_NyqNWnhX2xS0Svv2kfmH7n4yF2q"},{"@type":"CROSSREF","@value":"10.1021/acs.inorgchem.0c03222_references_DOI_NyqNWnhX2xS0Svv2kfmH7n4yF2q"},{"@type":"CROSSREF","@value":"10.1038/s41467-019-12414-z_references_DOI_NyqNWnhX2xS0Svv2kfmH7n4yF2q"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20170371_references_DOI_NyqNWnhX2xS0Svv2kfmH7n4yF2q"},{"@type":"CROSSREF","@value":"10.1038/s41598-024-62858-7_references_DOI_NyqNWnhX2xS0Svv2kfmH7n4yF2q"},{"@type":"CROSSREF","@value":"10.1021/acs.inorgchem.0c01710_references_DOI_NyqNWnhX2xS0Svv2kfmH7n4yF2q"}]}