{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262943379618688.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ange.201505730"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201505730"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201505730"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ange.201505730"}}],"dc:title":[{"@value":"Electrocatalytic Production of C3‐C4 Compounds by Conversion of CO<sub>2</sub> on a Chloride‐Induced Bi‐Phasic Cu<sub>2</sub>O‐Cu Catalyst"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Electrocatalytic conversion of carbon dioxide (CO<jats:sub>2</jats:sub>) has recently received considerable attention as one of the most feasible CO<jats:sub>2</jats:sub> utilization techniques. In particular, copper and copper‐derived catalysts have exhibited the ability to produce a number of organic molecules from CO<jats:sub>2</jats:sub>. Herein, we report a chloride (Cl)‐induced bi‐phasic cuprous oxide (Cu<jats:sub>2</jats:sub>O) and metallic copper (Cu) electrode (Cu<jats:sub>2</jats:sub>O<jats:sub>Cl</jats:sub>) as an efficient catalyst for the formation of high‐carbon organic molecules by CO<jats:sub>2</jats:sub> conversion, and identify the origin of electroselectivity toward the formation of high‐carbon organic compounds. The Cu<jats:sub>2</jats:sub>O<jats:sub>Cl</jats:sub> electrocatalyst results in the preferential formation of multi‐carbon fuels, including <jats:italic>n</jats:italic>‐propanol and <jats:italic>n</jats:italic>‐butane C3–C4 compounds. We propose that the remarkable electrocatalytic conversion behavior is due to the favorable affinity between the reaction intermediates and the catalytic surface.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382262943379618688","@type":"Researcher","foaf:name":[{"@value":"Seunghwa Lee"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943379618689","@type":"Researcher","foaf:name":[{"@value":"Dahee Kim"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943379618690","@type":"Researcher","foaf:name":[{"@value":"Jaeyoung Lee"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00448249"},{"@type":"EISSN","@value":"15213757"}],"prism:publicationName":[{"@value":"Angewandte Chemie"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-10-16","prism:volume":"127","prism:number":"49","prism:startingPage":"14914","prism:endingPage":"14918"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201505730"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201505730"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ange.201505730"}],"createdAt":"2015-10-16","modifiedAt":"2023-09-02","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1361694367878642432","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Role of a Hydroxide Layer on Cu Electrodes in Electrochemical CO<sub>2</sub> Reduction"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ange.201505730"},{"@type":"CROSSREF","@value":"10.1021/acscatal.9b00896_references_DOI_MYDM4adHvGvd6eOR53idz39vFD"}]}