{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262943479013760.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1126/science.1120411"}},{"identifier":{"@type":"URI","@value":"https://www.science.org/doi/pdf/10.1126/science.1120411"}}],"dc:title":[{"@value":"Porous, Crystalline, Covalent Organic Frameworks"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>\n            Covalent organic frameworks (COFs) have been designed and successfully synthesized by condensation reactions of phenyl diboronic acid {C\n            <jats:sub>6</jats:sub>\n            H\n            <jats:sub>4</jats:sub>\n            [B(OH)\n            <jats:sub>2</jats:sub>\n            ]\n            <jats:sub>2</jats:sub>\n            } and hexahydroxytriphenylene [C\n            <jats:sub>18</jats:sub>\n            H\n            <jats:sub>6</jats:sub>\n            (OH)\n            <jats:sub>6</jats:sub>\n            ]. Powder x-ray diffraction studies of the highly crystalline products (C\n            <jats:sub>3</jats:sub>\n            H\n            <jats:sub>2</jats:sub>\n            BO)\n            <jats:sub>6</jats:sub>\n            ·(C\n            <jats:sub>9</jats:sub>\n            H\n            <jats:sub>12</jats:sub>\n            )\n            <jats:sub>1</jats:sub>\n            (COF-1) and C\n            <jats:sub>9</jats:sub>\n            H\n            <jats:sub>4</jats:sub>\n            BO\n            <jats:sub>2</jats:sub>\n            (COF-5) revealed expanded porous graphitic layers that are either staggered (COF-1,\n            <jats:italic>P</jats:italic>\n            6\n            <jats:sub>3</jats:sub>\n            /\n            <jats:italic>mmc</jats:italic>\n            ) or eclipsed (COF-5,\n            <jats:italic>P</jats:italic>\n            6/\n            <jats:italic>mmm</jats:italic>\n            ). Their crystal structures are entirely held by strong bonds between B, C, and O atoms to form rigid porous architectures with pore sizes ranging from 7 to 27 angstroms. COF-1 and COF-5 exhibit high thermal stability (to temperatures up to 500° to 600°C), permanent porosity, and high surface areas (711 and 1590 square meters per gram, respectively).\n          </jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382262943479013888","@type":"Researcher","foaf:name":[{"@value":"Adrien P. Côté"}],"jpcoar:affiliationName":[{"@value":"Materials Design and Discovery Group, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109–1055, USA."},{"@value":"Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287–1604, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943479013892","@type":"Researcher","foaf:name":[{"@value":"Annabelle I. Benin"}],"jpcoar:affiliationName":[{"@value":"Materials Design and Discovery Group, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109–1055, USA."},{"@value":"Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287–1604, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943479013890","@type":"Researcher","foaf:name":[{"@value":"Nathan W. Ockwig"}],"jpcoar:affiliationName":[{"@value":"Materials Design and Discovery Group, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109–1055, USA."},{"@value":"Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287–1604, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943479013891","@type":"Researcher","foaf:name":[{"@value":"Michael O'Keeffe"}],"jpcoar:affiliationName":[{"@value":"Materials Design and Discovery Group, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109–1055, USA."},{"@value":"Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287–1604, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943479013889","@type":"Researcher","foaf:name":[{"@value":"Adam J. Matzger"}],"jpcoar:affiliationName":[{"@value":"Materials Design and Discovery Group, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109–1055, USA."},{"@value":"Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287–1604, USA."}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943479013760","@type":"Researcher","foaf:name":[{"@value":"Omar M. Yaghi"}],"jpcoar:affiliationName":[{"@value":"Materials Design and Discovery Group, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, MI 48109–1055, USA."},{"@value":"Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287–1604, USA."}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00368075"},{"@type":"EISSN","@value":"10959203"}],"prism:publicationName":[{"@value":"Science"}],"dc:publisher":[{"@value":"American Association for the Advancement of Science (AAAS)"}],"prism:publicationDate":"2005-11-18","prism:volume":"310","prism:number":"5751","prism:startingPage":"1166","prism:endingPage":"1170"},"reviewed":"false","url":[{"@id":"https://www.science.org/doi/pdf/10.1126/science.1120411"}],"createdAt":"2005-11-18","modifiedAt":"2024-01-10","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050018428980366848","@type":"Article","resourceType":"学術雑誌論文(journal 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