{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262943630972928.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.328296"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jap/article-pdf/51/8/4356/18388999/4356_1_online.pdf"}},{"identifier":{"@type":"NAID","@value":"80000689377"}}],"dc:title":[{"@value":"The role of B-site cation disorder in diffuse phase transition behavior of perovskite ferroelectrics"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>In Pb(Sc0.5Ta0.5)O3 it has been shown that the degree of order in the B-site Sc3+, Ta5+ cations can be controlled by suitable thermal annealing. For samples which have been well-ordered by long annealing, dielectric measurements on single crystals show a normal first-order ferroelectric phase change at 13 °C and a maximum low-temperature spontaneous polarization of 23.0 μc/cm2. With increasing disorder, the crystals begin to exhibit the classical diffuse phase transition of a ferroelectric relaxor, with a broad Curie range and strong low-frequency dielectric dispersion in the transition range. X-ray diffraction measurements of the size of the ordered microregions suggest that ordering proceeds by different mechanisms in single-crystal versus ceramic samples, though the resulting effects upon the dielectric behavior are very similar.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1582824501320247040","@type":"Researcher","foaf:name":[{"@value":"N. Setter"}],"jpcoar:affiliationName":[{"@value":"Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943630972928","@type":"Researcher","foaf:name":[{"@value":"L. E. Cross"}],"jpcoar:affiliationName":[{"@value":"Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00218979"},{"@type":"EISSN","@value":"10897550"},{"@type":"NCID","@value":"AA00693547"}],"prism:publicationName":[{"@value":"Journal of Applied Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"1980-08-01","prism:volume":"51","prism:number":"8","prism:startingPage":"4356","prism:endingPage":"4360"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jap/article-pdf/51/8/4356/18388999/4356_1_online.pdf"}],"createdAt":"2003-02-14","modifiedAt":"2024-02-04","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360009142497950464","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Correlation between depolarization temperature and lattice distortion in quenched 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