{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262943665679360.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ajoc.201500096"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fajoc.201500096"}},{"identifier":{"@type":"URI","@value":"https://aces.onlinelibrary.wiley.com/doi/pdf/10.1002/ajoc.201500096"}}],"dc:title":[{"@value":"Metal‐Free Direct Aryltrifluoromethylation of Allylic Alcohols with Langlois’ Reagent through Concomitant 1,2‐Aryl Migration"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A metal‐free and cost‐effective synthetic protocol for selective aryltrifluoromethylation of allylic alcohols with Langlois’ reagent (CF<jats:sub>3</jats:sub>SO<jats:sub>2</jats:sub>Na) through cascade trifluoromethyl radical addition/1,2‐aryl migration has been developed. The highlights of this procedure are operational simplicity, excellent functional group tolerance, and mild reaction conditions.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380298341944122112","@type":"Researcher","foaf:name":[{"@value":"Hong‐Li Huang"}],"jpcoar:affiliationName":[{"@value":"State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology  Harbin 150080 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943665679360","@type":"Researcher","foaf:name":[{"@value":"Hang Yan"}],"jpcoar:affiliationName":[{"@value":"State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology  Harbin 150080 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380298341944122113","@type":"Researcher","foaf:name":[{"@value":"Guo‐Lin Gao"}],"jpcoar:affiliationName":[{"@value":"State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology  Harbin 150080 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943665679363","@type":"Researcher","foaf:name":[{"@value":"Chao Yang"}],"jpcoar:affiliationName":[{"@value":"State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology  Harbin 150080 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943665679361","@type":"Researcher","foaf:name":[{"@value":"Wujiong Xia"}],"jpcoar:affiliationName":[{"@value":"State Key Lab of Urban Water Resource and Environment The Academy of Fundamental and Interdisciplinary Sciences Harbin Institute of Technology  Harbin 150080 P. R. China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"21935807"},{"@type":"EISSN","@value":"21935815"}],"prism:publicationName":[{"@value":"Asian Journal of Organic Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-04-27","prism:volume":"4","prism:number":"7","prism:startingPage":"674","prism:endingPage":"677"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fajoc.201500096"},{"@id":"https://aces.onlinelibrary.wiley.com/doi/pdf/10.1002/ajoc.201500096"}],"createdAt":"2015-04-07","modifiedAt":"2025-10-07","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/2050588892096788096","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkylation methods for synthesizing versatile building blocks"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ajoc.201500096"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190080_references_DOI_QKvH19zNlnuPr0Lg5YcElo6SrFK"}]}