{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262943696294784.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ejoc.200700572"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.200700572"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.200700572"}}],"dc:title":[{"@value":"The Aza‐Morita–Baylis–Hillman Reaction of <i>N</i>‐Thiophosphoryl Imines Catalyzed by 1,3,5‐Triaza‐7‐phosphaadamantane (PTA) –– Convenient Synthesis of α‐Methylene‐β‐Amino Ketone or Acid Derivatives"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>In the presence of an effective air‐stable nucleophilic trialkylphosphane orgaocatalyst, 1,3,5‐triaza‐7‐phosphaadamantane, <jats:italic>N</jats:italic>‐diethoxythiophosphorylimines <jats:bold>1</jats:bold> and <jats:italic>N</jats:italic>‐diphenylthiophosphinoylimines <jats:bold>2</jats:bold> exhibited good reactivity in the methyl vinyl ketone or methyl acrylate based aza‐Morita–Baylis–Hillman reaction. The corresponding products were obtained in fair‐to‐excellent chemical yields. Moreover, the chiral‐imine‐induced diastereoselective aza‐MBH reaction was also realized with 90 % <jats:italic>de</jats:italic>. This reaction provides a convenient method for the synthesis of synthetically valuable α‐methylene‐β‐amino ketone or acid derivatives.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382262943696294789","@type":"Researcher","foaf:name":[{"@value":"Xinyuan Xu"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943696294784","@type":"Researcher","foaf:name":[{"@value":"Chungui Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943696294788","@type":"Researcher","foaf:name":[{"@value":"Zhenghong Zhou"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943696294785","@type":"Researcher","foaf:name":[{"@value":"Xiaofang Tang"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943696294787","@type":"Researcher","foaf:name":[{"@value":"Zhengjie He"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943696294786","@type":"Researcher","foaf:name":[{"@value":"Chuchi Tang"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1434193X"},{"@type":"EISSN","@value":"10990690"}],"prism:publicationName":[{"@value":"European Journal of Organic Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2007-08-31","prism:volume":"2007","prism:number":"27","prism:startingPage":"4487","prism:endingPage":"4491"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.200700572"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.200700572"}],"createdAt":"2007-08-08","modifiedAt":"2025-10-14","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216612747008","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Stereoselective Total Synthesis of KAE609 via Direct Catalytic Asymmetric Alkynylation to Ketimine"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658179660160","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Direct Catalytic Asymmetric Alkynylation of Ketoimines"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714791998240896","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Recent advances in catalytic asymmetric C-C bond-forming reactions to ketimines promoted by metal-based catalysts"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ejoc.200700572"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.5b02300_references_DOI_8iZuDYVJ5jSwaXxvPJan4SeGUmU"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20140302_references_DOI_8iZuDYVJ5jSwaXxvPJan4SeGUmU"},{"@type":"CROSSREF","@value":"10.1021/ol3035609_references_DOI_8iZuDYVJ5jSwaXxvPJan4SeGUmU"}]}