{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262943760382976.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/asia.200800067"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fasia.200800067"}},{"identifier":{"@type":"URI","@value":"https://aces.onlinelibrary.wiley.com/doi/pdf/10.1002/asia.200800067"}}],"dc:title":[{"@value":"A Supported Rhodium Hydroxide Catalyst: Preparation, Characterization, and Scope of the Synthesis of Primary Amides from Aldoximes or Aldehydes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A supported rhodium hydroxide catalyst, Rh(OH)<jats:sub>x</jats:sub>/Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> (x=3), is prepared by the reaction of Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> with RhCl<jats:sub>3</jats:sub> in an aqueous medium followed by treatment with NaOH. The Rh<jats:sup>III</jats:sup> hydroxide species is monomerically (or highly) dispersed on the Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> support. Rh(OH)<jats:sub>x</jats:sub>/Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> acts as a reusable heterogeneous catalyst in water, rather than in an explosive, hazardous, and carcinogenic organic solvent, for the synthesis of primary amides from aldoximes or aldehydes by an efficient sequential process of dehydration and rehydration. The dehydrative condensation of aldehydes and hydroxylamine is also promoted by the Rh(OH)<jats:sub>x</jats:sub>/Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> catalyst.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382262943760382976","@type":"Researcher","foaf:name":[{"@value":"Hiroshi Fujiwara"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943760382980","@type":"Researcher","foaf:name":[{"@value":"Yoshiyuki Ogasawara"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943760382979","@type":"Researcher","foaf:name":[{"@value":"Miyuki Kotani"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943760382978","@type":"Researcher","foaf:name":[{"@value":"Kazuya Yamaguchi"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943760382977","@type":"Researcher","foaf:name":[{"@value":"Noritaka Mizuno"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"18614728"},{"@type":"EISSN","@value":"1861471X"}],"prism:publicationName":[{"@value":"Chemistry – An Asian Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2008-09","prism:volume":"3","prism:number":"8-9","prism:startingPage":"1715","prism:endingPage":"1721"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fasia.200800067"},{"@id":"https://aces.onlinelibrary.wiley.com/doi/pdf/10.1002/asia.200800067"}],"createdAt":"2008-06-09","modifiedAt":"2025-10-08","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283689402104832","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Supported Gold Nanoparticles for Efficient α‐Oxygenation of Secondary and Tertiary Amines into Amides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183520558080","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Green oxidative synthesis of primary amides from primary alcohols or aldehydes catalyzed by a cryptomelane-type manganese oxide-based octahedral molecular sieve, OMS-2"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846639395310080","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The “Borrowing Hydrogen Strategy” by Supported Ruthenium Hydroxide Catalysts: Synthetic Scope of Symmetrically and Unsymmetrically Substituted Amines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641805608960","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Manganese oxide-catalyzed transformation of primary amines to primary amides through the sequence of oxidative dehydrogenation and successive hydration"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205190167168","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Supported Metal Hydroxides as Efficient Heterogeneous Catalysts for Green Functional Group Transformations"},{"@language":"ja","@value":"担持金属水酸化物を基盤とした環境調和型官能基変換反応のための高機能固体触媒開発"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714792015489280","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Development of environmentally friendly dehydrogenative oxidation reactions using multifunctional heterogeneous catalysts"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/asia.200800067"},{"@type":"OPENAIRE","@value":"doi_dedup___::d4ec9adda7bc030726f496ad92b38912"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20220181_references_DOI_ZKtSPFO44QE2GSCTH2Lh1B7VC07"},{"@type":"CROSSREF","@value":"10.1002/anie.201602695_references_DOI_ZKtSPFO44QE2GSCTH2Lh1B7VC07"},{"@type":"CROSSREF","@value":"10.1039/c2cy20178j_references_DOI_ZKtSPFO44QE2GSCTH2Lh1B7VC07"},{"@type":"CROSSREF","@value":"10.1002/chem.201000149_references_DOI_ZKtSPFO44QE2GSCTH2Lh1B7VC07"},{"@type":"CROSSREF","@value":"10.1039/c2cc17499e_references_DOI_ZKtSPFO44QE2GSCTH2Lh1B7VC07"},{"@type":"CROSSREF","@value":"10.1627/jpi.57.251_references_DOI_ZKtSPFO44QE2GSCTH2Lh1B7VC07"}]}