{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262943944269696.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.tetlet.2010.06.051"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0040403910010440?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S0040403910010440?httpAccept=text/plain"}},{"identifier":{"@type":"DOI","@value":"10.1002/chin.201046067"}}],"dc:title":[{"@value":"Metal-free one-pot oxidative conversion of benzylic alcohols and benzylic halides into aromatic amides with molecular iodine in aq ammonia, and hydrogen peroxide"}],"description":[{"notation":[{"@value":"Various primary alcohols, particularly benzylic alcohols, could be converted into the corresponding aromatic amides in good yields in a one-pot manner by treatment with molecular iodine in aq. NH3, followed by reaction with ∼30% aq H2O2. Similarly, various benzylic halides could be also converted into the corresponding aromatic amides in good yields in a one-pot manner by treatment with molecular iodine in aq NH3, followed by reaction with ∼30% aq H2O2. The present reactions involve the metal-free one-pot oxidative conversion of benzylic alcohols and benzylic halides into the corresponding aromatic amides, respectively."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382262943944269697","@type":"Researcher","foaf:name":[{"@value":"Ryosuke Ohmura"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943944269696","@type":"Researcher","foaf:name":[{"@value":"Misato Takahata"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262943944269698","@type":"Researcher","foaf:name":[{"@value":"Hideo Togo"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00404039"},{"@type":"PISSN","@value":"09317597"},{"@type":"EISSN","@value":"15222667"}],"prism:publicationName":[{"@value":"Tetrahedron Letters"}],"dc:publisher":[{"@value":"Elsevier 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