{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262944554979584.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ejoc.201400087"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201400087"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.201400087"}}],"dc:title":[{"@value":"Synthesis of Oxindoles through Silver‐Catalyzed Trifluoromethylation–, Difluoromethylation– and Arylsulfonylation–Cyclization Reaction of <i>N</i>‐Arylacrylamides"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Efficient synthesis of trifluoromethyl and difluoromethyl‐substituted oxindoles was achieved by reacting Langlois reagent or Baran reagent with <jats:italic>N</jats:italic>‐arylacrylamides. However, the reaction of aryl sulfinic acid sodium salts with <jats:italic>N</jats:italic>‐arylacrylamides did not give the desulfinative products, instead, aryl sulfonated products were produced.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382262944554979588","@type":"Researcher","foaf:name":[{"@value":"Jidan Liu"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262944554979586","@type":"Researcher","foaf:name":[{"@value":"Shaobo Zhuang"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262944554979589","@type":"Researcher","foaf:name":[{"@value":"Qingwen Gui"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262944554979584","@type":"Researcher","foaf:name":[{"@value":"Xiang Chen"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262944554979585","@type":"Researcher","foaf:name":[{"@value":"Zhiyong Yang"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262944554979587","@type":"Researcher","foaf:name":[{"@value":"Ze Tan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1434193X"},{"@type":"EISSN","@value":"10990690"}],"prism:publicationName":[{"@value":"European Journal of Organic Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2014-04-04","prism:volume":"2014","prism:number":"15","prism:startingPage":"3196","prism:endingPage":"3202"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201400087"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.201400087"}],"createdAt":"2014-04-04","modifiedAt":"2025-10-15","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002214425440896","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216612956416","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The Direct C–H Difluoromethylation of Heteroarenes Based on the Photolysis of Hypervalent Iodine(III) Reagents That Contain Difluoroacetoxy Ligands"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641825849216","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Efficient generation of perfluoroalkyl radicals from sodium perfluoroalkanesulfinates and a hypervalent iodine(<scp>iii</scp>) reagent: mild, metal-free synthesis of perfluoroalkylated organic molecules"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848654923342976","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF<sub>2</sub>H‐Containing Alcohols"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892096788096","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkylation methods for synthesizing versatile building blocks"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ejoc.201400087"},{"@type":"CROSSREF","@value":"10.1002/anie.201604127_references_DOI_1Hwuef5SXOgbChi5cLkyb0UGn6n"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190080_references_DOI_1Hwuef5SXOgbChi5cLkyb0UGn6n"},{"@type":"CROSSREF","@value":"10.1039/c6ob01245k_references_DOI_1Hwuef5SXOgbChi5cLkyb0UGn6n"},{"@type":"CROSSREF","@value":"10.1002/chem.201504838_references_DOI_1Hwuef5SXOgbChi5cLkyb0UGn6n"},{"@type":"CROSSREF","@value":"10.1021/acs.orglett.7b02416_references_DOI_1Hwuef5SXOgbChi5cLkyb0UGn6n"}]}