{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262944789784064.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201408335"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201408335"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201408335"}}],"dc:title":[{"@value":"Rhodium‐Catalyzed NH Insertion of Pyridyl Carbenes Derived from Pyridotriazoles: A General and Efficient Approach to 2‐Picolylamines and Imidazo[1,5‐<i>a</i>]pyridines"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A general and efficient NH insertion reaction of rhodium pyridyl carbenes derived from pyridotriazoles was developed. Various NH‐containing compounds, including amides, anilines, enamines, and aliphatic amines, smoothly underwent the NH insertion reaction to afford 2‐picolylamine derivatives. The developed transformation was further utilized in a facile one‐pot synthesis of imidazo[1,5‐a]pyridines.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382262944789784064","@type":"Researcher","foaf:name":[{"@value":"Yi Shi"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262944789784066","@type":"Researcher","foaf:name":[{"@value":"Anton V. Gulevich"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262944789784065","@type":"Researcher","foaf:name":[{"@value":"Vladimir Gevorgyan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2014-10-21","prism:volume":"53","prism:number":"51","prism:startingPage":"14191","prism:endingPage":"14195"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201408335"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201408335"}],"createdAt":"2014-10-21","modifiedAt":"2023-10-16","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360846639356430848","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Enantioselective Denitrogenative Annulation of 1<i>H</i>‐Tetrazoles with Styrenes Catalyzed by Rhodium"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201408335"},{"@type":"CROSSREF","@value":"10.1002/anie.201801283_references_DOI_98Ksb2OYtHs2rU6LJHTSAcjJ1hY"}]}