Evidence from x-ray diffraction of orientational ordering in phase III of solid hydrogen at pressures up to 183 GPa

Yuichi Akahama, Manabu Nishimura, Haruki Kawamura, Naohisa Hirao, Yasuo Ohishi, Kenichi Takemura

doi:10.1103/physrevb.82.060101

Evidence from x-ray diffraction of orientational ordering in phase III of solid hydrogen at pressures up to 183 GPa

DOI Web Site Web Site 被引用文献6件

書誌事項

公開日: 2010-08-05

権利情報

http://link.aps.org/licenses/aps-default-license

DOI

10.1103/physrevb.82.060101

公開者: American Physical Society (APS)

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説明

X-ray powder-diffraction experiments on solid hydrogen are performed at pressures up to 183 GPa and low temperature of 100 K. A transition into phase III is confirmed by in situ Raman-scattering measurements. Two diffraction peaks corresponding to the 100 and 101 lines of the hcp structure are observed above the II-III phase-transition pressure of 160 GPa, indicating that the hydrogen molecules in phases II and III are still in the vicinity of the hcp lattice point up to 183 GPa. Assuming a hexagonal structure for these phases, the lattice parameter, $c$ decreases by 1.5% at the II-III phase transition. The behavior is consistent with a theoretically proposed feature of classical orientational ordering of rotating hydrogen molecules for phase III.