{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262945494255488.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.1742146"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/23/5/909/18806690/909_1_online.pdf"}},{"identifier":{"@type":"NAID","@value":"30015729813"}}],"dc:title":[{"@value":"O – O Bond Dissociation Energies in Propionyl and Butyryl Peroxides"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The kinetics of the decomposition of gaseous propionyl and butyryl peroxides was studied in a flow system. It was found that both compounds decompose in a unimolecular manner. The rate constant for the decomposition of propionyl peroxide is given by the equation k=2.5·1014·exp(−30 000/RT),and that for butyryl peroxide by the equation k=1.9·1014·exp(−29 600/RT).It is concluded that D(C2H5·CO·O−O·CO·C2H5)≃D(C3H7·CO·O−O·CO·C3H7)≃30·kcal/mole.The fates of the ethyl and propyl radicals produced in the decomposition are discussed.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1580572699076419200","@type":"Researcher","foaf:name":[{"@value":"A. Rembaum"}],"jpcoar:affiliationName":[{"@value":"Chemistry Department, State University of New York, College of Forestry, Syracuse 10, New York"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262945494255488","@type":"Researcher","foaf:name":[{"@value":"M. Szwarc"}],"jpcoar:affiliationName":[{"@value":"Chemistry Department, State University of New York, College of Forestry, Syracuse 10, New York"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"1955-05-01","prism:volume":"23","prism:number":"5","prism:startingPage":"909","prism:endingPage":"913"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/23/5/909/18806690/909_1_online.pdf"}],"createdAt":"2005-04-22","modifiedAt":"2024-02-08","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Physical%20and%20Theoretical%20Chemistry","dc:title":"Physical and Theoretical Chemistry"},{"@id":"https://cir.nii.ac.jp/all?q=General%20Physics%20and%20Astronomy","dc:title":"General Physics and Astronomy"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283694076043008","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The Reactions of Aroyl Peroxides with Grignard Reagents. II. Relative Reactivities of Substituted Benzoyl Peroxides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169057689984","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Reactivities of Stable Rotamers XXXVII : Thermolyses and Photolyses of 2(1<i>H</i>)-Thioxo-1-pyridyl 3-(1,4-Dimethyl-9-triptycyl)-3-methylbutanoate Rotamers"}]},{"@id":"https://cir.nii.ac.jp/crid/1571135649643822464","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Reactivities of Stable Rotamers XXXVII : Thermolyses and Photolyses of 2(1H)-Thioxo-1-pyridyl 3-(1, 4-Dimethyl-9-triptycyl)-3-methylbutanoate Rotamers^<1, 2)>"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1063/1.1742146"},{"@type":"CIA","@value":"30015729813"},{"@type":"CROSSREF","@value":"10.1246/bcsj.69.177_references_DOI_LKXlAJNFYJB6ji5YnHZSv3trnin"},{"@type":"CROSSREF","@value":"10.1246/bcsj.44.125_references_DOI_LKXlAJNFYJB6ji5YnHZSv3trnin"}]}