{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362262945643533952.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ejic.200400763"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejic.200400763"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200400763"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ejic.200400763"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200400763"}}],"dc:title":[{"@value":"Experimental and Theoretical Studies of Homoleptic Tellurium Cyanides Te(CN)<sub><i>x</i></sub>: Crystal Structure of Te(CN)<sub>2</sub>"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The labile tellurium cyanide species Te(CN)<jats:sub>2</jats:sub> and Te(CN)<jats:sub>4</jats:sub> have been prepared by treatment of tellurium(<jats:sc>IV</jats:sc>) tetrahalides with cyanide. Both are thermosensitive solids and, in addition, the tetracyanide was found to be pyrophoric. The crystal structure of Te(CN)<jats:sub>2</jats:sub> has been determined. The structures of Te(CN)<jats:sub>2</jats:sub>, Te(CN)<jats:sub>4</jats:sub>, and Te(CN)<jats:sub>6</jats:sub> have been calculated at various levels of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382262945643533956","@type":"Researcher","foaf:name":[{"@value":"Thomas M. Klapötke"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262945643533952","@type":"Researcher","foaf:name":[{"@value":"Burkhard Krumm"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262945643533954","@type":"Researcher","foaf:name":[{"@value":"Juan Carlos Gálvez‐Ruiz"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262945643533953","@type":"Researcher","foaf:name":[{"@value":"Heinrich Nöth"}]},{"@id":"https://cir.nii.ac.jp/crid/1382262945643533955","@type":"Researcher","foaf:name":[{"@value":"Ingo Schwab"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14341948"},{"@type":"EISSN","@value":"10990682"}],"prism:publicationName":[{"@value":"European Journal of Inorganic Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2004-12","prism:volume":"2004","prism:number":"24","prism:startingPage":"4764","prism:endingPage":"4769"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejic.200400763"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200400763"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ejic.200400763"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200400763"}],"createdAt":"2004-12-09","modifiedAt":"2025-10-13","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360016862108078080","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Solid‐State Assembly by Chelating Chalcogen Bonding in Quinodimethane Tetraesters Fused with a Chalcogenadiazole"}]},{"@id":"https://cir.nii.ac.jp/crid/1360579816407399680","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Crystal Engineering, Electron Conduction, Molecular Recognition and Reactivity by Chalcogen Bonds in Tetracyanoquinodimethanes Fused with [1,2,5]Chalcogenadiazoles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360851398328117248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"[1,2,5]Chalcogenadiazole-fused Dicyanonaphthoquinodiimines: Larger Contribution from Chalcogen Bond than Weak Hydrogen Bond in Determining Crystal Structures"}]},{"@id":"https://cir.nii.ac.jp/crid/1360853567516316800","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular Recognition by Chalcogen Bond: Selective Charge‐Transfer Crystal Formation of Dimethylnaphthalene with Selenadiazolotetracyanonaphthoquinodimethane"}]},{"@id":"https://cir.nii.ac.jp/crid/1360861289342143360","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Chalcogen-Peierls Transition: Single-Crystal-to-Single-Crystal Transition from a Two-Dimensional to a One-Dimensional Network of Chalcogen Bonds at Low Temperature"}]},{"@id":"https://cir.nii.ac.jp/crid/2050307417131931776","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Chalcogen bond versus halogen bond : changing contributions in determining the crystal packing of dihalobenzochalcogenadiazoles"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/ejic.200400763"},{"@type":"CROSSREF","@value":"10.1002/cplu.202200075_references_DOI_KLDjCN1s7fN2g9iFdMSO3NYefzm"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20220008_references_DOI_KLDjCN1s7fN2g9iFdMSO3NYefzm"},{"@type":"CROSSREF","@value":"10.1246/cl.210095_references_DOI_KLDjCN1s7fN2g9iFdMSO3NYefzm"},{"@type":"CROSSREF","@value":"10.1002/ejoc.202001554_references_DOI_KLDjCN1s7fN2g9iFdMSO3NYefzm"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20230091_references_DOI_KLDjCN1s7fN2g9iFdMSO3NYefzm"},{"@type":"CROSSREF","@value":"10.1055/a-2072-2951_references_DOI_KLDjCN1s7fN2g9iFdMSO3NYefzm"}]}