{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362544418314975360.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/chem.201602855"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201602855"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201602855"}}],"dc:title":[{"@value":"Electron‐Catalyzed Fluoroalkylation of Vinyl Azides"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The transition‐metal free fluoroalkylation of vinyl azides is herein reported. This operationally simple reaction employs the Togni reagent as a CF<jats:sub>3</jats:sub> source, Bu<jats:sub>4</jats:sub>NI as an initiator, and occurs under electron catalysis. A range of readily prepared starting materials are functionalized using this approach to produce both phenanthridines and quinoxalin‐2‐ones.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382544418314975360","@type":"Researcher","foaf:name":[{"@value":"Emily G. Mackay"}],"jpcoar:affiliationName":[{"@value":"Westfälische Wilhelms Universität Organisch-Chemisches Institut  Corrensstrasse 40 48149 Münster Germany"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544418314975361","@type":"Researcher","foaf:name":[{"@value":"Armido Studer"}],"jpcoar:affiliationName":[{"@value":"Westfälische Wilhelms Universität Organisch-Chemisches Institut  Corrensstrasse 40 48149 Münster Germany"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09476539"},{"@type":"EISSN","@value":"15213765"}],"prism:publicationName":[{"@value":"Chemistry – A European Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2016-07-19","prism:volume":"22","prism:number":"38","prism:startingPage":"13455","prism:endingPage":"13458"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201602855"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201602855"}],"createdAt":"2016-07-05","modifiedAt":"2025-10-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360853567577200768","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Energy transfer-driven regioselective synthesis of functionalized phenanthridines by visible-light Ir photocatalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892096788096","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkylation methods for synthesizing versatile building blocks"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/chem.201602855"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190080_references_DOI_IaPn02dRsznuImXRvnluBT1FJ2i"},{"@type":"CROSSREF","@value":"10.1039/d0qo00271b_references_DOI_IaPn02dRsznuImXRvnluBT1FJ2i"}]}