{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362544419155144192.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1039/c3cy00211j"}},{"identifier":{"@type":"URI","@value":"http://pubs.rsc.org/en/content/articlepdf/2013/CY/C3CY00211J"}}],"dc:title":[{"@value":"Efficient hydrogen production and photocatalytic reduction of nitrobenzene over a visible-light-responsive metal–organic framework photocatalyst"}],"description":[{"notation":[{"@value":"Efficient hydrogen production and photocatalytic reduction of nitrobenzene were achieved by using a Pt-deposited amino-functionalised Ti(IV) metal–organic framework (Pt/Ti-MOF-NH2) under visible-light irradiation. XRD and N2 adsorption measurements revealed that crystalline microporous structures were formed and maintained even after the Pt deposition. The photocatalytic activity for the visible-light-promoted hydrogen production was improved through the optimization of the deposition amount of Pt as a cocatalyst. The optimised amount of Pt was determined to be 1.5 wt%. The results of in situ ESR measurements clearly indicate that the reaction proceeds through the electron transfer from the organic linker to deposited Pt as a cocatalyst by way of titanium-oxo clusters. In addition, the Pt/Ti-MOF-NH2 photocatalyst was found to catalyse photocatalytic reduction of nitrobenzene under visible-light irradiation. It was also confirmed that the catalyst can be reused at least three times without significant loss of its catalytic activity."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382544419155144065","@type":"Researcher","foaf:name":[{"@value":"Takashi Toyao"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419155144064","@type":"Researcher","foaf:name":[{"@value":"Masakazu Saito"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419155144069","@type":"Researcher","foaf:name":[{"@value":"Yu Horiuchi"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419155144192","@type":"Researcher","foaf:name":[{"@value":"Katsunori Mochizuki"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419155144068","@type":"Researcher","foaf:name":[{"@value":"Masatoshi Iwata"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419155144067","@type":"Researcher","foaf:name":[{"@value":"Hideyuki Higashimura"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419155144066","@type":"Researcher","foaf:name":[{"@value":"Masaya Matsuoka"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"20444753"},{"@type":"EISSN","@value":"20444761"}],"prism:publicationName":[{"@value":"Catalysis Science & Technology"}],"dc:publisher":[{"@value":"Royal Society of Chemistry (RSC)"}],"prism:publicationDate":"2013","prism:volume":"3","prism:number":"8","prism:startingPage":"2092"},"reviewed":"false","url":[{"@id":"http://pubs.rsc.org/en/content/articlepdf/2013/CY/C3CY00211J"}],"createdAt":"2013-04-25","modifiedAt":"2024-04-17","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216880547456","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Recent advances in visible-light-responsive photocatalysts for hydrogen production and solar energy conversion – from semiconducting TiO2 to MOF/PCP photocatalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216880916736","@type":"Article","resourceType":"学術雑誌論文(journal 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