{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362544419224767360.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/adfm.201606422"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.201606422"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.201606422"}}],"dc:title":[{"@value":"3D Porous Cu Current Collector/Li‐Metal Composite Anode for Stable Lithium‐Metal Batteries"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Lithium‐metal batteries are of particular interest for next‐generation electrical energy storage because of their high energy density on both volumetric and gravimetric bases. Effective strategies to stabilize the Li‐metal anode are the prerequisite for the progress of these exceptional storage technologies, such as Li–S and Li–O<jats:sub>2</jats:sub> batteries. Various challenges, such as uneven Li electrodeposition, anode volume expansion, and dendrite‐induced short‐circuit have hindered the practical application of rechargeable Li‐metal batteries. Herein, a one‐step facile and cost‐effective strategy for stabilizing lithium‐metal batteries via 3D porous Cu current collector/Li‐metal composite anode is reported. The porous structure of the composite electrode provides a “cage” for the redeposition of “hostless” lithium and accommodates the anode volume expansion during cycling. Compared with planar Cu foil, its high specific surface area favors the electrochemical reaction kinetics and lowers the local current density along the anode. It leads to low interfacial resistance and stabilizes the Li electrodeposition. On this basis, galvanostatic measurements are performed on both symmetric cells and Li/Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> cells and it is found that the electrodes exhibit exceptional abilities of promoting cell lifetime and stabilizing the cycling behavior. Although this work focuses on lithium metal, this novel tactic is easy to generalize to other metal electrodes.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382544419224767362","@type":"Researcher","foaf:name":[{"@value":"Qi Li"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Chemical Engineering Institute of Pharmaceutical Engineering College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419224767360","@type":"Researcher","foaf:name":[{"@value":"Shoupu Zhu"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Chemical Engineering Institute of Pharmaceutical Engineering College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419224767361","@type":"Researcher","foaf:name":[{"@value":"Yingying Lu"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Chemical Engineering Institute of Pharmaceutical Engineering College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1616301X"},{"@type":"EISSN","@value":"16163028"}],"prism:publicationName":[{"@value":"Advanced Functional Materials"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2017-03-21","prism:volume":"27","prism:number":"18"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.201606422"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.201606422"}],"createdAt":"2017-03-22","modifiedAt":"2025-10-06","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360009142768678912","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The Insights of Lithium Metal Plating/Stripping in Porous Hosts: Progress and Perspectives"}]},{"@id":"https://cir.nii.ac.jp/crid/1360857593775939328","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Lithium Metal Anode for High-Power and High-Capacity Rechargeable Batteries"}]},{"@id":"https://cir.nii.ac.jp/crid/1390564227327420032","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Preparation of a High-Performance Nanocrystalline Lithium/Graphene Composite Battery via High-Pressure Torsion Method"}]},{"@id":"https://cir.nii.ac.jp/crid/2051151842066404480","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Ag2S-modified 3D carbon cloth as a dendrite suppressing framework for high energy lithium-sulfur batteries"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/adfm.201606422"},{"@type":"CROSSREF","@value":"10.1002/ente.202000700_references_DOI_ItWNzlVNGvGmUaXPqt4rbYuLYST"},{"@type":"CROSSREF","@value":"10.1246/cl.220057_references_DOI_ItWNzlVNGvGmUaXPqt4rbYuLYST"},{"@type":"CROSSREF","@value":"10.21926/jept.2102019_references_DOI_ItWNzlVNGvGmUaXPqt4rbYuLYST"},{"@type":"CROSSREF","@value":"10.2320/matertrans.mt-m2019142_references_DOI_ItWNzlVNGvGmUaXPqt4rbYuLYST"}]}