{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362544419624150784.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.3762/bjoc.10.1"}},{"identifier":{"@type":"URI","@value":"https://www.beilstein-journals.org/bjoc/articles/10/1"}},{"identifier":{"@type":"URI","@value":"https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-10-1.pdf"}},{"identifier":{"@type":"URI","@value":"http://www.beilstein-journals.org/bjoc/content/10/1/1"}}],"dc:title":[{"@value":"Synthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3<i>H</i>-1λ<sup>3</sup>,2-benziodaoxol-3-one"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The synthesis of 5-nitro-1-(trifluoromethyl)-3<jats:italic>H</jats:italic>-1λ<jats:sup>3</jats:sup>,2-benziodaoxol-3-one (<jats:bold>3</jats:bold>), a hypervalent-iodine-based electrophilic trifluoromethylating reagent, is described. Whereas considerations based on cyclic voltammetry and X-ray structural properties would predict an inferior reactivity when compared to the non-nitrated derivative <jats:bold>2</jats:bold>, <jats:sup>19</jats:sup>F NMR kinetic studies showed that this new derivative is almost one order of magnitude more reactive. Furthermore, differential scanning calorimetry measurements indicated that, in addition, it is also safer to handle.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382544419624150784","@type":"Researcher","foaf:name":[{"@value":"Nico Santschi"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419624150788","@type":"Researcher","foaf:name":[{"@value":"Roman C Sarott"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419624150785","@type":"Researcher","foaf:name":[{"@value":"Elisabeth Otth"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419624150787","@type":"Researcher","foaf:name":[{"@value":"Reinhard Kissner"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544419624150786","@type":"Researcher","foaf:name":[{"@value":"Antonio Togni"}]}],"publication":{"publicationIdentifier":[{"@type":"EISSN","@value":"18605397"}],"prism:publicationName":[{"@value":"Beilstein Journal of Organic Chemistry"}],"dc:publisher":[{"@value":"Beilstein Institut"}],"prism:publicationDate":"2014-01-02","prism:volume":"10","prism:startingPage":"1","prism:endingPage":"6"},"reviewed":"false","dc:rights":["http://creativecommons.org/licenses/by/2.0","http://creativecommons.org/licenses/by/2.0","http://creativecommons.org/licenses/by/2.0"],"url":[{"@id":"https://www.beilstein-journals.org/bjoc/articles/10/1"},{"@id":"https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-10-1.pdf"},{"@id":"http://www.beilstein-journals.org/bjoc/content/10/1/1"}],"createdAt":"2014-01-02","modifiedAt":"2021-06-22","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360567182230026752","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of CF3-containing oxazolines via trifluoromethylation of allylamides with Togni reagent in the presence of alkali metal iodides"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892096788096","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Fluoroalkylation methods for synthesizing versatile building blocks"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.3762/bjoc.10.1"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20190080_references_DOI_GZCmAqhAHkzfh0kUYaK1DONWuZ2"},{"@type":"CROSSREF","@value":"10.1016/j.jfluchem.2017.07.012_references_DOI_GZCmAqhAHkzfh0kUYaK1DONWuZ2"}]}