{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1362544420200959232.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/cjoc.201500905"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcjoc.201500905"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/cjoc.201500905"}}],"dc:title":[{"@value":"Nucleophilic Trifluoromethylthiolation of Alkyl Chlorides, Bromides and Tosylates"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A direct nucleophilic trifluoromethylthiolation of alkyl chlorides, bromides and tosylates with AgSCF<jats:sub>3</jats:sub> was described. It was found that the presence of <jats:italic>n</jats:italic>Bu<jats:sub>4</jats:sub>NI or a combination of <jats:italic>n</jats:italic>Bu<jats:sub>4</jats:sub>NI/<jats:italic>n</jats:italic>Bu<jats:sub>4</jats:sub>NBr significantly enhanced the reaction rates. The reaction conditions were mild, thus allowing the tolerance of a variety of functional groups.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1382544420200959104","@type":"Researcher","foaf:name":[{"@value":"Chunfa Xu"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544420200959232","@type":"Researcher","foaf:name":[{"@value":"Qingyun Chen"}]},{"@id":"https://cir.nii.ac.jp/crid/1382544420200959105","@type":"Researcher","foaf:name":[{"@value":"Qilong Shen"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1001604X"},{"@type":"EISSN","@value":"16147065"}],"prism:publicationName":[{"@value":"Chinese Journal of Chemistry"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2016-03-08","prism:volume":"34","prism:number":"5","prism:startingPage":"495","prism:endingPage":"504"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fcjoc.201500905"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/cjoc.201500905"}],"createdAt":"2016-03-08","modifiedAt":"2023-09-10","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390001204142494208","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"},{"@value":"Award Accounts : The Chemical Society of Japan Award for Creative Work for 2014 : Development of Shelf-Stable Reagents for Fluoro-Functionalization Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/cjoc.201500905"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160223_references_DOI_ThMJ1Z4Twft9smHnncHQJe5760A"}]}